Phase Transfer Catalysis and Separation of Organometallic Catalyst

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (6): 513-517. Previous Articles Next Articles

金属络合物的相转移催化分析与分离

纪红兵;王乐夫

华南理工大学

发布日期:2003-06-25

Phase Transfer Catalysis and Separation of Organometallic Catalyst

Ji Hongbing;Wang Lefu

School of Chemical Engieering,South China University of Technology

Published:2003-06-25

Abstract

The development of recyclable process for organometallic catalysts by simple phase separation has been reviewed . Selective dissolution of catalyst in one liquid phase while substrate and product in the other can be attained by choosing suitable solvent. A homogeneous reaction and two-phase separation process were achieved. By tuning the reaction temperature, this method has been successfully applied in temperature-dependent aqueous biphasic and fluorous biphasic systems with fluorous or organometallic catalyst.

Key words: PHASE TRANSFER CATALYSIS;CATALYTIC ACTIVITY;WATER;FLUORINE, ORGANIC COMPOUNDS

CLC Number:

O621

Cite this article

Ji Hongbing;Wang Lefu. Phase Transfer Catalysis and Separation of Organometallic Catalyst[J]. Chin. J. Org. Chem., 2003, 23(6): 513-517.

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[1]	Shen Yumei;Shi Min. New Developments of Carbon Dioxide Fixation [J]. Chin. J. Org. Chem., 2003, 23(1): 22-29.
[2]	Hua Jianli;Li Jun;Luo Jingdong;Qin Jingui. Recent Progress in Molecular Design of Organic Second-Order Nonlinear Optical Chromophores with Both Large First-Order Molecular Hyperpolarizability and Good Transparency [J]. Chin. J. Org. Chem., 2003, 23(1): 44-53.
[3]	Li Jian;Cui Wenjin;Wang Li;Yang Yajiang. Gelation and thermodynamics of a polymerizable gelator for organic fluids [J]. Chin. J. Org. Chem., 2002, 22(9): 651-657.
[4]	Fu Nanyan;Cao Zhong;Yuan Yaofeng;Wang Jitao. Self-assembly of organoindium compounds [J]. Chin. J. Org. Chem., 2002, 22(2): 107-114.
[5]	Zeng Heping;Li Yue. Synthesis of heterocyclic sulfur ligands [J]. Chin. J. Org. Chem., 2002, 22(11): 879-883.
[6]	Chen Xinbing;An Zhongwei. Progresses in the fluorination addition reactions of unsaturated carbon-carbon bonds [J]. Chin. J. Org. Chem., 2002, 22(10): 694-701.
[7]	Shen Yanchang. New synthetic methodotogies based on the participation of organometallic and elementorganic compounds [J]. Chin. J. Org. Chem., 2001, 21(11): 816-823.
[8]	Wang Congmin;Pan Guilan;Zhao Lihua;Fan Ping;Meng Xianjuan;Ming Yangfu;Fan Meigong. Advances and prospects of organic photochromics [J]. Chin. J. Org. Chem., 2001, 21(11): 954-961.
[9]	Cao Chenzhong. Estimation of the ionization potential for amines, alcohols and ethers [J]. Chin. J. Org. Chem., 1999, 19(6): 616-620.
[10]	CHEN HONGZHENG;WANG MANG;YANG SHILIN. Study on the molecular design of organic photoconductive materials [J]. Chin. J. Org. Chem., 1996, 16(3): 227-231.
[11]	CAO CHENZHONG. The hydrophobic index of alkyl group [J]. Chin. J. Org. Chem., 1996, 16(2): 133-138.
[12]	DING WEIYU. Reactions of phosphonic and arsenic ylides with electron deficient alkynes and synthesis of polyfunctional organo-fluoro compounds [J]. Chin. J. Org. Chem., 1995, 15(1): 17-29.
[13]	ZENG LONGMEI. Recent prgress on the research of marine natural products [J]. Chin. J. Org. Chem., 1989, 9(5): 402-413.
[14]	CHEN JIAN;ZHOU XUNJUN. Recent progress in organoselenium and organotellurium chemistry [J]. Chin. J. Org. Chem., 1987, 7(5): 331-341.
[15]	YING BAIPING;QIN GUOWEI;XU RENSHENG. Application of CD exciton chirality method in organic chemistry [J]. Chin. J. Org. Chem., 1987, 7(3): 165-173.

金属络合物的相转移催化分析与分离

Phase Transfer Catalysis and Separation of Organometallic Catalyst

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