Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (7): 650-653. Previous Articles     Next Articles

N-3-炔丁烯基咔唑的合成及热聚合

王斌;谢守和;叶大铿;张声华   

  1. 华中农业大学食科系;军事经济学院军需系;中山大学化学系
  • 发布日期:2003-07-25

Synthesis and Thermal Polymerization of N-3-Yne-butenylcarbazole

Wang Bin;Xie Shouhe;Ye Daken;Zhang Shenghua   

  1. Department of Food Science, Huazhong Agriculture University;Institute of Nutrition, College of Military Economics;Department of Chemistry, Zhongshan University
  • Published:2003-07-25

N-3-Yne-butenylcarbazole has been synthesized by stirring a mixture of carbazole, 1,4-dichloro-2-butyne, benzene, 50% NaOH and cetyl trimethyl ammonium bromide in water. The compound was polymerized by heating. The polymerization activated energy was 118 kj/mol. Molecular weight of the polymer polymerized at 120 t! was 1.9 x l(r (n ?a9). The conductance ratio of the polymer was less than 10 ~12 S? cm~' and that of the charge transfer compound of the polymer with FeCl3 was 8 x 10 ~4 S ? cm"1.

Key words: CARBAZOLE P;CTAB;PHASE TRANSFER CATALYSIS;SODIUM HYDROXIDE, BUTYNE P;RECRYSTALLIZATION;IR;1HNMR;MS;CHARGE TRANSFER COMPLEX

CLC Number: