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Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (2): 216-218. Previous Articles     Next Articles

低价钛引起的芳酮肟的反应

史达清*, 赵红, 王香善, 屠树江   

  1. 徐州师范大学化学系 徐州 221009
  • 收稿日期:2002-10-15 修回日期:2003-08-01 接受日期:2003-08-26 发布日期:2022-09-20
  • 基金资助:
    江苏省教育厅自然科学基金(No. 001KJB150008)资助项目.

Reaction of Aromatic Ketoxime Induced by Low-valent Titanium

SHI, Da-Qing*, ZHAO, Hong, WANG, Xiang-Shan, TU, Shu-Jiang   

  1. Department of Chemistry, Xuzhou Normal University, Xuzhou 221009
  • Received:2002-10-15 Revised:2003-08-01 Accepted:2003-08-26 Published:2022-09-20
  • Contact: * E-mail: dqshi@xznu.edu.cn

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When substituted phenyl methyl ketoximes were treated with low-valent titanium (TiCl4/Sm) the deoximation reaction giving ketones in high yields took place, whereas in the case of diaryl ketoximes, diaryl ketones, amine or Schiff base were formed.

Key words: low-valent titanium reagent, aromatic ketoxime, deoximation