Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (4): 374-379. Previous Articles     Next Articles

各种烯基锆化合物的合成及其在立体选择性合成二(三)取代的烯烃中的应用

钟平   

  1. 温州师范学院化学系 温州 325027
  • 收稿日期:2003-04-25 修回日期:2003-08-18 接受日期:2003-09-04 发布日期:2022-09-19
  • 基金资助:
    国家自然科学基金(No. 20272043)和浙江省自然科学基金(No. 201015)资助项目

Synthesis of Various Vinylzirconium Compounds and Their Application in Stereoselective Synthesis of Di- and Tri-substituted Alkenes

ZHONG, Ping   

  1. Department of Chemistry, Wenzhou Normal College, Wenzhou325027
  • Received:2003-04-25 Revised:2003-08-18 Accepted:2003-09-04 Published:2022-09-19
  • Contact: *E-mail: zhongp0512@sina.com.cn

Disubstituted and trisubstituted alkenes were prepared stereoselectively via thereaction of vinylzirconium, selanylvinylzirconium, stannylvinylzirconium, vinylzirconium sulfone, vinylzirconium sulfoxide and silylvinylzirconium compounds, which were achieved in high yields and high stereoselectivity via hydrozirconation of the corresponding compounds with various electrophilic reagents.

Key words: vinylzirconium compound, Schwartz's reagent, hydrozirconation, stereoselective synthesis