Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (12): 1565-1569. Previous Articles     Next Articles

Original Articles

相转移催化条件下N-苯甲酰基-N'-芳基硒脲类化合物的合成及其超分子晶体结构

魏太保,王海,林奇,张有明*   

  1. (1西北师范大学化学化工学院 甘肃省高分子材料重点实验室 兰州 730070)
    (2内蒙古师范大学化学与环境科学学院 呼和浩特 010022)
  • 收稿日期:2004-12-16 修回日期:2005-06-29 发布日期:2005-11-30
  • 通讯作者: 张有明

Synthesis of N-Benzoyl-N'-arylselenoureas under Phase Transfer Catalysis Conditions and Supramolecular Crystal Structure

WEI Tai-Bao, WANG Hai, LIN Qi, ZHANG You-Ming*   

  1. (1 College of Chemistry and Chemical Engineering, Gansu Key Laboratory of Polymer Materi-als,
    Northwest Normal University, Lanzhou 730070)
    (2 College of Chemical and Environmental Science, Inner Mongolia Normal University, Huhhot 010022)
  • Received:2004-12-16 Revised:2005-06-29 Published:2005-11-30
  • Contact: ZHANG You-Ming

Benzoyl chloride was treated with potassium selenocyanate in dichloromethane by using polyethylene glycal-400 as the solid-liquid phase transfer catalyst to yield the corresponding benzoyl isoselenocyanate. This intermediate did not need to be isolated and directly reacted with arylamines, affording the N-benzoyl-N'-arylselenoureas 2a2p. These compounds were characterized by IR, 1H NMR spectra and elemental analysis and the single crystal structure of 2k has been confirmed by X-ray crystallographic analysis. In the crystal, the compound was assem-bled to a linear supramolecular structure along axis a by the intermolecular hydrogen bonds. The crystal belongs to the monoclinic crystal system with P2(1)/c space group and a=1.1073(1) nm, b=0.5745(1) nm, c=2.4356(5) nm, β=92.10(1)°, V=1.5483(4) nm3, Z=4, μ=2.428.

Key words: supramolecular crystal structure, phase transfer catalysis, N-benzoyl-N'-arylselenourea