HPLC/MSn Analysis of Triterpenoid Saponins from Anemone rupestris ssp. gelida

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (01): 116-119. Previous Articles Next Articles

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冻地银莲花中三萜皂苷的HPLC/MSⁿ分析

周燕¹，李锐¹，王兴明²，彭树林¹，丁立生*^,1

(¹中国科学院成都生物研究所成都 610041)
(²西南科技大学化学与生物工程系绵阳 621002)

收稿日期:2005-02-21 修回日期:2005-07-15 发布日期:2005-12-31
通讯作者: 丁立生

HPLC/MSⁿ Analysis of Triterpenoid Saponins from Anemone rupestris ssp. gelida

ZHOU Yan¹,LI Rui¹,WANG Xing-Ming²,PENG Shu-Lin¹,DING Li-Sheng*^,1

(¹ Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041)
(² Department of Chemistry and Biology Engineering, Southwest University of Science and Technology, Mianyang 621002)

Received:2005-02-21 Revised:2005-07-15 Published:2005-12-31
Contact: DING Li-Sheng

Abstract

High performance liquid chromatography coupled with on-line tandem mass spectrometry (HPLC/MSⁿ) was applied to characterization of triterpenoid saponins in the whole plant of Anemone rupestris ssp. gelida. By using ESI-MSⁿ analysis and comparison retention time with those of authentic samples, 11 major triterpenoid saponins were identified as hederacholichiside F (1), leontoside D (2), kalopanaxsaponin B (3), hederacholichiside E (4), cauloside D (5), hederasaponin B (6), ciwujianoside C₃(7), leontoside B (8), kalopanaxsaponin A (9), akebia saponin D (10) and oleanolic acid 3-rhamnosyl-(12)- [glucosyl-(14)]arabinoside (11). Among them, the saponins of 2, 5, 7, 10 and 11 were found from this plant for the first time.

Key words: triterpenoid saponin, HPLC/MSⁿ, analysis, Anemone rupestris ssp. Gelida

Cite this article

ZHOU Yan,LI Rui,WANG Xing-Ming²,PENG Shu-Lin,DING Li-Sheng*^{,1. HPLC/MSⁿ Analysis of Triterpenoid Saponins from Anemone rupestris ssp. gelida[J]. Chin. J. Org. Chem., 2006, 26(01): 116-119.}

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冻地银莲花中三萜皂苷的HPLC/MSⁿ分析

HPLC/MSⁿ Analysis of Triterpenoid Saponins from Anemone rupestris ssp. gelida

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冻地银莲花中三萜皂苷的HPLC/MSn分析