Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (01): 51-55. Previous Articles     Next Articles

Original Articles

麝香草的新单萜配糖物的分离与合成

陆占国*,1,竹内宏之2   

  1. (1哈尔滨商业大学化学中心 哈尔滨150076)
    (2日本萜化学株式会社 神户 658-0031 日本)
  • 收稿日期:2005-03-15 修回日期:2005-07-05 发布日期:2005-12-31
  • 通讯作者: 陆占国

Synthesis and Isolation of a New Monoterpene Glucoside from Thyme

LU Zhan-Guo*,1,TAKEUCHI Hiroyuki2   

  1. (1 Chemical Center of Harbin University of Commerce, Harbin 150076, China)
  • Received:2005-03-15 Revised:2005-07-05 Published:2005-12-31
  • Contact: LU Zhan-Guo

Three monoterpene glucosides were isolated from the methanol extract of thyme (Thymus vul-garis L.). They were identified as p-cymen-9-yl-β-D-glucopyranoside (1), 5-β-D-glucopyranosylthymoquinol (2) and 2-β-D-glucopyranosylthymoquinol (3) by spectral evidence. 1 is a new compound, but 2 and 3 are known compounds. The stereochemistry at C-8 of 1 was elucidated to be R-form by enantioselective synthesis from p-cymen-9-ol.

Key words: thyme, monoterpene glucoside, p-cymen-9-yl-β-D-glucopyranoside