Progress in the Photochromic Mechanism of Spirooxazine

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (07): 1012-1023. Previous Articles

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螺噁嗪光致变色反应机理研究进展

冯长根*^,1，王建营¹,2

(¹北京理工大学爆炸科学与技术国家重点实验室北京 100081)
(²解放军总装备部防疫防护大队北京 100101)

收稿日期:2005-06-24 修回日期:2006-01-23 发布日期:2006-07-01
通讯作者: 冯长根

Progress in the Photochromic Mechanism of Spirooxazine

FENG Chang-Gen*^,1,2,WANG Jian-Ying¹,2

(¹State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technol-ogy, Beijing 100081)
(² Military Unit of Epidemic Prevention and Protection, Head-quarters of General Equipment,
The People’s Liberation Army of China, Beijing 100101)

Received:2005-06-24 Revised:2006-01-23 Published:2006-07-01
Contact: FENG Chang-Gen

Abstract

The study on photochemistry and photophysics of spirooxazines in the photochromic reactions has been the focus since the middle of 1980s. The photochromic mechanism of spirooxazines, which was studied in different medium the past 20 years, such as solution, crystal or solid, was reviewed. The new experimental methods, technologies and theory applied to study the photochromic process of spirooxazines were mainly introduced, and the substitution effects on the photochromic properties were analyzed. The typical examples were used to explain the important steering meaning on the study of design, synthesis and applications.

Key words: photochromic mechanism, kinetics, substitution effect, spirooxazine

Cite this article

FENG Chang-Gen*^,1,2,WANG Jian-Ying^1,2. Progress in the Photochromic Mechanism of Spirooxazine[J]. Chin. J. Org. Chem., 2006, 26(07): 1012-1023.

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螺噁嗪光致变色反应机理研究进展

Progress in the Photochromic Mechanism of Spirooxazine

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