A New Multifunctional Redox-Fluorescence Switch Based onTetrathiafulvalene and Binaphthyl Units

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (11): 1533-1538. Previous Articles Next Articles

Original Articles

四硫富瓦烯和联萘基构建的新型多功能氧化还原荧光开关

王永秋，迟兴宝*

(淮北煤炭师范学院化学系淮北 235000)

收稿日期:2005-12-22 修回日期:1900-01-01 发布日期:2006-10-27
通讯作者: 迟兴宝

A New Multifunctional Redox-Fluorescence Switch Based onTetrathiafulvalene and Binaphthyl Units

WANG Yong-Qiu,CHI Xing-Bao*

(Department of Chemistry, Huaibei Coal Industry Teachers College, Huaibei 235000)

Received:2005-12-22 Revised:1900-01-01 Published:2006-10-27
Contact: CHI Xing-Bao

Abstract

A new redox fluorescence switch based on tetrathiafulvalene and binaphthyl units was synthesized by 3-bromomethyl-2,2'-bis(methoxymethyloxy)-1,1'-binaphthalene and tetrathiafulvalene tetrathiolates. Its fluorescence can be reversibly modulated by sequential electrochemical oxidation and reduction. So it is a new redox fluorescence switch. It may selectively recognize and detect Fe^3＋by cyclic volt-ammetry.

Key words: tetrathiaflvalene, binaphthyl, cyclic voltammetry, redox fluorescence switch

Cite this article

WANG Yong-Qiu,CHI Xing-Bao*. A New Multifunctional Redox-Fluorescence Switch Based onTetrathiafulvalene and Binaphthyl Units[J]. Chin. J. Org. Chem., 2006, 26(11): 1533-1538.

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四硫富瓦烯和联萘基构建的新型多功能氧化还原荧光开关

A New Multifunctional Redox-Fluorescence Switch Based onTetrathiafulvalene and Binaphthyl Units

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