Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (05): 814-818. Previous Articles     Next Articles

Original Articles

二{2-{2-{9-乙基-6-[2-(8-羟基喹啉-2-基)乙烯基]咔唑-3-基}乙烯}-8-羟基喹啉}锌配合物的合成与荧光光谱特性

方晴,曾和平*,张卫民,张培全   

  1. (华南理工大学化学科学学院功能分子研究所 广州 510641)
  • 收稿日期:2007-06-28 修回日期:2007-10-08 发布日期:2008-05-20
  • 通讯作者: 曾和平

Synthesis and Fluorescence of Bis{2-{2-{9-ethyl-6-[2-(8-hydroxy-quinolin-2-yl)vinyl]carbazol-3-yl}vinyl}-8-quinolinolato} Zn Complex

FANG Qing,ZENG He-Ping*,ZHANG Wei-Min,ZHANG Pei-Quan   

  1. (Institute of Functional Molecules, South China University of Tochnology, Guangzhou 510641)
  • Received:2007-06-28 Revised:2007-10-08 Published:2008-05-20
  • Contact: ZENG He-Ping

3,6-Bis[2-(8-hydroxyquinolin-2-yl)vinyl]carbazole (4) and its Zn(II) complex 5 have been synthesized, and the former was identified by 1H NMR, FTIR, MS spectra and elemental analyses. Their photoluminescence properties were measured on an F-2500 spectrometer. The results show that compound 4 is green-emitting (500 nm) and the fluorescence spectrum is obviously red-shifted at room temperature. Meanwhile, the fluorescene properties were discussed. The emission peak of compound 5 is at 600 nm and shows obvious red-shift compared with 2-methyl-8-quinolinolato zinc complex.

Key words: 3,6-bis[2-(8-hydroxyquinolin-2-yl)vinyl]carbazole, fluorescence property, 2-methyl-8-hydroxyquinoline