Synthesis of 3,3-Arylidene bis(4-hydroxycoumarin) Catalyzed by Sulfamic Acid in Aqueous Media under Microwave Irradiation

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (12): 1988-1991. Previous Articles Next Articles

Notes

微波辐射下氨磺酸催化水相合成3,3-亚芳基双(4-羟基香豆素)

周建峰^*,a,b,c；贡桂霞^b；安礼涛^a；孙小军^a；朱凤霞^a

(a淮阴师范学院化学系淮安 223300 )
(b苏州大学化学化工学院苏州 215123)
(c江苏省低维材料化学重点建设实验室淮安 223300）

收稿日期:2008-04-23 修回日期:2008-07-25 发布日期:2009-07-07
通讯作者: 周建峰 E-mail:zhoujf@sohu.com

Synthesis of 3,3-Arylidene bis(4-hydroxycoumarin) Catalyzed by Sulfamic Acid in Aqueous Media under Microwave Irradiation

Zhou, Jianfeng^*,a,b,c；Gong, Guixia^b；An, Litao^a；Sun, Xiaojun^a；Zhu, Fengxia^a

(^a Department of Chemistry, Huaiyin Teachers College, Huaian 223300) (^b School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215123)
(^c Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaian 223300)

Received:2008-04-23 Revised:2008-07-25 Published:2009-07-07

Abstract

A series of 3,3-arylidene bis(4-hydroxycoumarins) with 75%～96% yields were synthesized by the reaction of aromatic aldehydes with 4-hydroxycoumarin using sulfamic acid as catalyst in aqueous media under microwave irradiation. The procedure has the advantages of high yield, short reaction time, environmental begin and easy work-up. Their structures were confirmed by IR, 1H NMR, 13C NMR spectra and elemental analysis.

Key words: 3,3-arylidene bis(4-hydroxycoumarin), 4-hydroxycoumarin, aromatic aldehyde, sulfamic acid, microwave irradiation, green synthesis

Cite this article

ZHOU Jian-Feng, GONG Gui-Xia, AN Li-Chao, SUN Xiao-Jun, SHU Feng-Xia. Synthesis of 3,3-Arylidene bis(4-hydroxycoumarin) Catalyzed by Sulfamic Acid in Aqueous Media under Microwave Irradiation[J]. Chin. J. Org. Chem., 2009, 29(12): 1988-1991.

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微波辐射下氨磺酸催化水相合成3,3-亚芳基双(4-羟基香豆素)

Synthesis of 3,3-Arylidene bis(4-hydroxycoumarin) Catalyzed by Sulfamic Acid in Aqueous Media under Microwave Irradiation

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