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Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (01): 120-123. Previous Articles Next Articles
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欧阳歆,张 祚,阳年发*
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国家自然科学基金;国家级.国家自然科学基金
Ouyang,Xin,Zhang,Zuo,Yang,Nianfa*
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Menthyl bromide and neomenthyl bromide were synthesized from L-menthol via highly stereoselective bromination reactions。When a mixture of concentrated hydrobromic acid and anhydrous zinc bromide was used as the brominating agent,menthyl bromide was stereoselectively formed。Neomenthyl bromide was highly stereoselectively obtained in the circumstance of using phosphorus tribromide as a brominating agent.
Key words: L-menthol, menthyl bromide, neomenthyl bromide, highly stereoselective transformation
OU Yang-Xin, ZHANG Zuo, YANG Nian-Fa. Synthesis of Menthyl Bromide and Neomenthyl Bromide by Highly Stereoselective Transformations[J]. Chin. J. Org. Chem., 2010, 30(01): 120-123.
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