Progress in ESI-MS Study for the Catalytic Asymmetric Reactions

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (06): 809-815. Previous Articles Next Articles

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电喷雾质谱法研究不对称催化反应进展

赵志雄，姚胜军，王昊阳*，郭寅龙*

中国科学院上海有机化学研究所上海质谱中心上海 200032

收稿日期:2009-06-30 修回日期:2009-12-18 发布日期:2010-02-23
通讯作者: 王昊阳 E-mail:haoyangwang@mail.sioc.ac.cn

Progress in ESI-MS Study for the Catalytic Asymmetric Reactions

ZHAO Zhi-Xiong, YAO Sheng-Jun, WANG Hao-Yang, GUO Yin-Long

Shanghai Mass Spectrometry Center, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032

Received:2009-06-30 Revised:2009-12-18 Published:2010-02-23
Contact: WANG Hao-Yang E-mail:haoyangwang@mail.sioc.ac.cn

Abstract

The utility of ESI-MS for studying the enantioselectivity of catalytic asymmetric reactions by measurement of the ee value of product or the different intensity of reactive intermediates/complexes involved in the asymmetric reactions, and the further evaluating and screening chiral catalysts would be discussed in this review.

Key words: mass spectrometry, electrospray ionization method, catalytic asymmetric reaction, ee value, reactive intermediate

Cite this article

ZHAO Zhi-Xiong, YAO Sheng-Jun, WANG Hao-Yang, GUO Yin-Long. Progress in ESI-MS Study for the Catalytic Asymmetric Reactions[J]. Chin. J. Org. Chem., 2010, 30(06): 809-815.

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电喷雾质谱法研究不对称催化反应进展

Progress in ESI-MS Study for the Catalytic Asymmetric Reactions

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