Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (5): 478-480. Previous Articles     Next Articles

Original Articles

N-三甲基硅基对甲苯磺酰胺与对甲苯磺酸酯的反应

荣国斌;王Bing;马汝建   

  1. 华东理工大学化学系.上海(200237);中国科学院上海有机化学研究所.上海 (200032)
  • 发布日期:1998-10-25

The reactions of N-trimethylsilyl-p-toluenesulfonamide with tosylates

Rong Guobin;WANG Bi;Ma Rujian   

  1. East China Univ of Sci Tech., Dept Chem.Shanghai(200237);Shanghai Inst Organ Chem., CAS.Shanghai(200032)
  • Published:1998-10-25

N-p-Tosyl-mopholine or N-p-tosyl-tetrahydropyrrole and N-methyl- p- toluenesulfonamide were prepared by the reactions of N- trimethylsilyl- p-toluenesulfonamide with 3-oxa-1, 5-pentadiol ditosylate or 1, 4- butadiol ditosylate and methyl p-tosylate respectively. The possible pathway was suggested.

Key words: TRANSITION STATE, ALKYLSULFONATE, P-METHYLBENZENESULFONIC ACID P, REACTION PATH, SULFONYL GROUP, P-METHYLBENZENESULFONIC ACID P, SIX MEMBER RING HETEROCYCLICS COMPOUNDS, TRIMETHYLSIL ANES, BENZENESULFONAMIDE P, P-METHYLBENZENESULFONIC ACID P

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