share
Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (2): 184-189. Previous Articles Next Articles
Original Articles
陈立功;李阳;孟Yi;李渊;吕萌;罗会兵;王勇
发布日期:
Chen Ligong;Li Yang;MENG ;Li Yuan;Lu Meng;Luo Huibing;Wang Yong
Published:
Share
Methyl 5, 9, 13-trimethylbutadeca-5, 9, 13-trienoate (3) and methyl 5-hexenates (7-9) were synthesized by homologation of 4, 8, 12- trimethyl-4, 8, 12-tridecatrienal (1) and 4-pentenals. Thus, treatment of 4-pentenals with methoxy methylenetriphenylphosphin afforded a mixture of cis- and trans- enol ethers, which were oxidized by PCC to give methyl 5-hexenates.
Key words: OXIDATION REACTION
CLC Number:
O621
Chen Ligong;Li Yang;MENG ;Li Yuan;Lu Meng;Luo Huibing;Wang Yong. Synthesis of methyl 5-hexenates by homologation of 4-pentenals[J]. Chin. J. Org. Chem., 1999, 19(2): 184-189.
Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks