Chin. J. Org. Chem. ›› 2002, Vol. 22 ›› Issue (11): 926-928. Previous Articles    

醋酸烯丙酯选择性地合成烯丙基硒醚

赵华绒,赵新建, 黄宪   

  • 发布日期:2002-11-25

An alternative synthesis of allylic selenides from allylic acetates

Zhao Huarong;Zhao Xinjian;Huang Xian   

  1. Department of Chemistry, Zhejiang University,Hanzhou(310027);State Center of Supervision and Test of Chemical Building Materials,Hangzhou (310013)
  • Published:2002-11-25

Allylic acetates were readily converted to corresponding allylic selenides by reduction with Pd-(PPh_3)_4-SmI_2 and subsequent treatment with arylselenenyl bromides.

Key words: ARYL GROUP;SELENIUM;BROMIDE;PALLADIUM COMPLEX;POLARITY;REVERSE, REACTION SELECTIVITY;SYNTHESIS

CLC Number: