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Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (04): 643-647. Previous Articles Next Articles
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赵 莹*; 叶翠层; 谭晓燕; 杨 志
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Zhao, Ying* ; Ye, Cuiceng; Tan, Xiaoyan; Yang, Zhi
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Michael addition reactions of acrylonitrile with p-substituted anilines have been carried out under various experimental conditions in the presence of AlCl3, AlCl3-NaOAc, or AlCl3-ZnCl2, resulting in N-β-cyanoethyl-p-substitutional anilines and N,N-bis(2-cyanoethyl)-p-substitutional anilines in high yields. And all of N,N-bis(2-cyanoethyl)-p-substituted anilines have been characterized by thermogravimetry, ultra-violet absorption spectrum, fourier transform infrared spectroscopy, electron paramagnetic resonance spec-tra, and elemental analyses.
Key words: N-β-cyanoethyl-p-substituted aniline, AlCl3, N,N-bis(2-cyanoethyl)-p-substituted aniline
Zhao, Ying* ; Ye, Cuiceng; Tan, Xiaoyan; Yang, Zhi. Anilination of Acrylonitrile with p-Substituted Anilines Catalyzed by AlCl3[J]. Chin. J. Org. Chem., 2009, 29(04): 643-647.
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