Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (12): 1375-1379. Previous Articles     Next Articles

乳液聚合型品红成色剂的合成

许煦;黄德音   

  1. 华东理工大学化学工程学院;上海交通大学化学化工学院
  • 发布日期:2003-12-25

Synthesis of Latex Magenta Couplers

Xu Xu;Huang Deyin   

  1. School of Chemical Engineering,East China University of Science and Technology;School of Chemistry and Chemical Engineering,Shanghai Jiaotong University
  • Published:2003-12-25

l-(2',4',6'-Trichlorophenyl)-3-amino-5-pyrazolone (3) was synthesized by the condensation of 2,4,6-trichlorophenyl-hydrazine with ethyl β-ethoxy-β-imino-propinate in the presence of sodium ethoxide. Three monomers of the couplers were obtained by the reaction of 3 or its 4-position derivatives with methacryloyl chloride. Three latex magenta couplers were formed by emulsion copolymerization of these monomers and butyl acrylate. The reaction intermediates and the monomers were characterized by IR and ' H NMR spectra. Some factors of affecting the reactions mentioned above were discussed.

Key words: PHENYLHYDRAZINE P;PYRAZOLINE P;EMULSION POLYMERIZATION;IR, CONDENSATION REACTION;PYRAZOLONE P

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