Clean Synthesis of Benzo[ h ]chromene Derivatives in Water

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (12): 1419-1421. Previous Articles Next Articles

水中苯并[h]色烯衍生物的洁净合成

史达清;张姝;庄启亚;王香善;屠树江;胡宏纹

徐州师范大学化学系;南京大学化学系

发布日期:2003-12-25

Clean Synthesis of Benzo[ h ]chromene Derivatives in Water

Shi Daqing;Zhang Shu;Zhuang Qiya;Wang Xiangshan;Tu Shujiang;Hu Hongwen

Department of Chemistry,Xuzhou Normal University;Department of Chemistry,Nanjing University

Published:2003-12-25

Abstract

A series of 2-amino-3-cyano-4-aiylbenzo[ ft ] chromenes were synthesized by the reaction of arylmethlene malononitrile with 1- naphthol in the presence of triethylbenzylammoniurn chloride (TEBA) in water. The structures of all products were characterized by elemental analysis, IR and !H NMR spectra. Compared to the previous methods, this new protocol has the advantages of high yields, inexpensive medium and environmental friendlyness.

Key words: benzo[h]chromene;NAPHTHALENOL;PROPANEDINITRILE P;TEBA;ADDITION REACTION, CYCLIZATION;ELEMENTAL ANALYSIS;IR;1HNMR

CLC Number:

O621

Cite this article

Shi Daqing;Zhang Shu;Zhuang Qiya;Wang Xiangshan;Tu Shujiang;Hu Hongwen. Clean Synthesis of Benzo[ h ]chromene Derivatives in Water[J]. Chin. J. Org. Chem., 2003, 23(12): 1419-1421.

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水中苯并[h]色烯衍生物的洁净合成

Clean Synthesis of Benzo[ h ]chromene Derivatives in Water

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