Synthesis and Crystal Structure of Drum Organooxotin Cluster from Carboxylic Acid: Hexameric Phenyloxotin 3-Indolpropylcarboxylate

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (3): 291-295. Previous Articles Next Articles

含羧酸配体的鼓形有机锡氧簇合物：六聚苯基锡氧3-吲哚丁酸酯的合成及晶体结构

尹汉东;王传华;马春林;房海霞

聊城大学化学系

发布日期:2003-03-25

Synthesis and Crystal Structure of Drum Organooxotin Cluster from Carboxylic Acid: Hexameric Phenyloxotin 3-Indolpropylcarboxylate

Yin HanDong;Wang,Chuanhua;Ma,Chunlin;Fang Haixia

Deportment of Chemistry,Linocheng University

Published:2003-03-25

Abstract

A novel drum organooxotin cluster hexameric phenyloxotin 3- indolpropylcarboxylate was synthesized by the reaction of H^SnOH with 3- indolpropylcarboxylic acid in 1:1 molar ratio. The crystal structures were determined by X-ray single crystal diffraction analysis. The crystal belongs to triclinic with space group P-1, a = 1.1722(6) nm, 6 = 1.5694(8) nm, c = 1.7227(9) nm, a = 116.251(8~)°, β= 100.854(10) ~°, 7 = 95.606(9)~°, Z=l, V = 2.732(3) nm~3, D-c = 1.554 g-cnT3, // = 1.420 imT~1, F(OOO) = 1276, R=0.0630, wR=0.0162. In crystal, the tin atoms rendered six-coordinated in a distorted octahedron geometry.

Key words: ORGANO TIN COMPOUND;CLUSTER COMPOUND;INDOLEBUTYRIC ACID;CRYSTAL STRUCTURE, ELEMENTAL ANALYSIS;IR;XRD;STRUCTURE CHARACTERISTICS

CLC Number:

O627

Cite this article

Yin HanDong;Wang,Chuanhua;Ma,Chunlin;Fang Haixia. Synthesis and Crystal Structure of Drum Organooxotin Cluster from Carboxylic Acid: Hexameric Phenyloxotin 3-Indolpropylcarboxylate[J]. Chin. J. Org. Chem., 2003, 23(3): 291-295.

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含羧酸配体的鼓形有机锡氧簇合物：六聚苯基锡氧3-吲哚丁酸酯的合成及晶体结构

Synthesis and Crystal Structure of Drum Organooxotin Cluster from Carboxylic Acid: Hexameric Phenyloxotin 3-Indolpropylcarboxylate

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