Synthesis of 2,4,6-Tri (arylamino)-l, 3,5-triazine Derivatives and Microwave Irradiation Effect

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (4): 380-383. Previous Articles Next Articles

2，4，6-三〔芳基氨基)-1，3，5-三嗪衍生物的合成方法和微波效应研究

沙耀武;董玉毅;韩涛

清华大学化学系

发布日期:2003-04-25

Synthesis of 2,4,6-Tri (arylamino)-l, 3,5-triazine Derivatives and Microwave Irradiation Effect

Sha YaoWu;Dong YuYi;Han Tao

Department of Chemistry, Tsinghua University

Published:2003-04-25

Abstract

Some 2,4, 6-tri(arylamino)-l, 3, 5-triazine derivatives were synthesized in high yields from 2,4,6-trichloro-1, 3, 5-triazine and a little excess of aromatic amines in 1,4-dioxane using sodium hydrogencarbonate as base. Comparing to literature, this method is mild and easy for operation and productive. The reaction rate was accelerated by at least ten times under microwave irradiation in comparision with that under common heating. The structures of synthesized compounds were determined by elemental analysis, FAB-MS and IR spectra.

Key words: TRIAZINE P;MICROWAVE RADIATION;DIOXANE;SODIUM BICARBONATE, AROMATIC AMINES;ELEMENTAL ANALYSIS;MS;IR

CLC Number:

O621

Cite this article

Sha YaoWu;Dong YuYi;Han Tao. Synthesis of 2,4,6-Tri (arylamino)-l, 3,5-triazine Derivatives and Microwave Irradiation Effect[J]. Chin. J. Org. Chem., 2003, 23(4): 380-383.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	MA Cha, LI Long, SUN Jin-Sheng, ZHAO Feng, LI Yi-Long. Recent Progress in Dansyl-Based Dendrimers [J]. Chin. J. Org. Chem., 2011, 31(12): 1977-1988.
[2]	LIU Bin, XIE Long-Guan, XU Xiao-Hua, LI Yong-Hong. Synthesis, Crystal Structure and Herbicidal Activity of 3-Benzoyl-4-hydroxycoumarin Derivatives [J]. Chin. J. Org. Chem., 2011, 31(12): 2067-2073.
[3]	WANG Gang-Qiang, CHEN Yu-Ling, HAN Ming-Song, SUN Liang, WANG Qiu-An. Synthesis and Biological Activity of Pterostilbene and 3-Methoxy Pterostilbene and Their Glucosides Derivatives [J]. Chin. J. Org. Chem., 2011, 31(12): 2114-2120.
[4]	ZHANG Hua-Cheng, LIU Zhao-Na, XIN Fei-Fei, LI Yue-Ming, KONG Li, HAO Ai-You. Atom Transfer Radical Polymerization Based on Cyclodextrin [J]. Chin. J. Org. Chem., 2011, 31(11): 1761-1772.
[5]	ZHANG Huan, LI Hai-Gang, WU Hai-Hong. Synthesis of Chiral Imidazolinone-Based Ionic Liquids [J]. Chin. J. Org. Chem., 2011, 31(9): 1433-1439.
[6]	. Synthesis and Antitumor Activity of 5,6-2H-[1,2,4]- triazolo [3,4-b][1,3,4]thiadiazine derivatives [J]. Chin. J. Org. Chem., 2011, 31(06): 912-920.
[7]	YI Bing, ZHANG Yang, SHU Xiao-Ma, YANG Yan, DU Wen-Le, LIU Zhan-Peng. Study on Henry Reaction Catalyzed by Dendritic Amines [J]. Chin. J. Org. Chem., 2011, 31(06): 874-877.
[8]	WEI Ben-Mei, ZHANG Zhi-Yong, DAI Zhi-Qun, ZHANG Kai-Cheng. Friedel-Crafts Benzylation of Aromatic Compounds Catalyzed by Chloroapatite Supported Metal Halides [J]. Chin. J. Org. Chem., 2011, 31(03): 392-396.
[9]	LIU Zhi-Chang, LIU Xiao-Xia, WANG Ying-Hong, YANG Lu. Synthesis and Biological Activities of N-Coumarin-3-formacyl-N - substitute Thioreas De-rivatives [J]. Chin. J. Org. Chem., 2011, 31(01): 136-140.
[10]	FAN Wen-Ming, GAO Jian-Rong, JIA Jian-Hong, HAN Liang, SHENG Wei-Jian, LI Yu-Jin. Solvent-Free Synthesis of β-Enamino Ketones (Esters) under High-Speed Vibration Miling (HSVM) Condition [J]. Chin. J. Org. Chem., 2010, 30(11): 1732-1736.
[11]	WANG Chao, ZHENG Xue-Fang, ZHANG Qian, LIU Qun. Progress in the Study of Different Position Substituted Thia-zolidine-4-carboxylic Acid and Its Derivatives [J]. Chin. J. Org. Chem., 2010, 30(10): 1441-1454.
[12]	XIONG Wen-Shuo, WANG Hong, YI Yu, MEI Jian-Feng, YING Guo-Qing. Progress of Crystallization-Induced Asymmetric Transformation in Resolution of Chiral Compounds [J]. Chin. J. Org. Chem., 2010, 30(07): 951-957.
[13]	YANG Xu-Hong, WU Ming-Hu, DING Ming-Wu. Synthesis of 2,2 -Disubstituted Bis(3-arylquinazolin-4(3H)-one)s [J]. Chin. J. Org. Chem., 2010, 30(07): 1032-1038.
[14]	LIU Chang-Chun, LU Wei-Ping, YAN Yan-Ning. Synthesis of Carbamates by Carbonylation of Floronitrobenzenes over TiO₂ Supported Pd-Fe Catalyst [J]. Chin. J. Org. Chem., 2010, 30(06): 843-848.
[15]	CAO Chen-Zhong, LIU Li-Qiu, CHEN Guan-Fan, ZHOU Zai-Chun, JIANG Rong-Qing, LEI Bing-Chao. Effect of Substituents on the Configuration of Stilbene Derivatives in Wittig Reaction of Substituted Benzaldehyde with Nitro-benzyltriphenylphosphonium Salt [J]. Chin. J. Org. Chem., 2010, 30(03): 395-400.

2，4，6-三〔芳基氨基)-1，3，5-三嗪衍生物的合成方法和微波效应研究

Synthesis of 2,4,6-Tri (arylamino)-l, 3,5-triazine Derivatives and Microwave Irradiation Effect

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments