Synthesis and Crystal Structure of Di-n-butyltin Bis (diphenylthiocarbazone)

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (6): 595-600. Previous Articles Next Articles

含硫、氮配位的二正丁基锡二（二苯基卡巴腙）合成及晶体结构研究

马春林;李凤;张如芬;尹汉东

聊城师范学院化学系

发布日期:2003-06-25

Synthesis and Crystal Structure of Di-n-butyltin Bis (diphenylthiocarbazone)

Ma Chunlin;Li Feng;Zhang Rufen;Yin handong

Department of Chemistry,Liaocheng Teachers University

Published:2003-06-25

Abstract

The compound ( n-Bu)_2Sn(SN_4C_13Hn)_2 was prepared by the reaction of di-n-butyltin dichloride or tri-Ti-butyltin chloride with diphenylthiocarbazone in the presence of the sodium alcoholic. Its structure was determined with IR, ~1H NMR, UV spectra and X-ray crystallography analysis. It crystallizes in the monoclinic, space group P2_1/c, 0=2.0215(7) mn, b = 1.3103(5) nm, c= 2.8171(10) nm, β = 95.472(7)°, Z = 8, V = 7.428(5) nm~3, D_c = 1.330g/cm~3,μ =0.834 mm~ (-1).

Key words: ORGANO TIN COMPOUNDS;HYDRAZONE;CRYSTAL STRUCTURE;ELEMENTAL ANALYSIS, IR;UV;1HNMR;STRUCTURE CHARACTERISTICS

CLC Number:

O621

Cite this article

Ma Chunlin;Li Feng;Zhang Rufen;Yin handong. Synthesis and Crystal Structure of Di-n-butyltin Bis (diphenylthiocarbazone)[J]. Chin. J. Org. Chem., 2003, 23(6): 595-600.

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含硫、氮配位的二正丁基锡二（二苯基卡巴腙）合成及晶体结构研究

Synthesis and Crystal Structure of Di-n-butyltin Bis (diphenylthiocarbazone)

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