Synthesis and Crystal Structure of 2,3-Dibenzo-1,4,6-triazabicyclo [3.3.1]-2-nonenemonomuriate

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (7): 710-713. Previous Articles Next Articles

2，3－二苯基－1，4，6－三氮杂二环[3.3.1]－2－壬烯单盐酸盐的合成及晶体结构

王虎林;薛岗林;徐媛;王兰英;王文亮;胡怀民

西北大学化学系;陕西师范大学化学系;中国科学院化学研究所

发布日期:2003-07-25

Synthesis and Crystal Structure of 2,3-Dibenzo-1,4,6-triazabicyclo [3.3.1]-2-nonenemonomuriate

Wang Hulin;Xue Ganglin;Xu Yuan;Wang Lanying;Wang Wenliang;Hu Huaimin

Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University;Department of Chemistry, Shaanxi Normal University;Institute of Chemistry, Chinese Academy of Sciences

Published:2003-07-25

Abstract

The azo-cycle compound, 2,3-dibenzo-l, 4,6-triazabicyclo [3.3.1 ] - 2-nonenemonomuriate, was prepared by condensation of benzil with dienthyltriamine in methanol and in the presence of Z1OCI2, and was characterized by !H NMR, IR and UV-vis spectra. Its crystal structure was determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group P2j/c, cell parameters: a = 1.69341(6) nm, b = 0.77564(3) nm, c = 1.21000(4) nm, /? = 96.1880(10)°, Z = 4, Dc = 1.319 g- cm"3. The compound is a non-planar aza-bicyclo compound with partial unsaturated bonds. The parent hexatomic ring is a chair conformation and the other six-member ring is a half-chair form.

Key words: NITROGEN HETEROCYCLICS;NONENE P;CRYSTAL STRUCTURE;1HNMR;IR;UV, XRD

CLC Number:

O621

Cite this article

Wang Hulin;Xue Ganglin;Xu Yuan;Wang Lanying;Wang Wenliang;Hu Huaimin. Synthesis and Crystal Structure of 2,3-Dibenzo-1,4,6-triazabicyclo [3.3.1]-2-nonenemonomuriate[J]. Chin. J. Org. Chem., 2003, 23(7): 710-713.

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2，3－二苯基－1，4，6－三氮杂二环[3.3.1]－2－壬烯单盐酸盐的合成及晶体结构

Synthesis and Crystal Structure of 2,3-Dibenzo-1,4,6-triazabicyclo [3.3.1]-2-nonenemonomuriate

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