Chin. J. Org. Chem. ›› 1988, Vol. 8 ›› Issue (6): 525-527. Previous Articles     Next Articles

一种使羧酸增加两个碳原子的合成方法

洪琳;郭红云;徐锦江   

  1. 杭州大学化学系
  • 发布日期:1988-12-25

A synthetic method of chain extension of two carbons for the carboxylic acid

HONG LIN;GUO HONGYUN;XU JINJIANG   

  • Published:1988-12-25

Reaction of Et acrylate with carboxylic acids RCO2H (R = alkyl, PhCH2) in ammonium peroxydisulfate in the presence of catalytic amts. of silver nitrate gave esters RCH2CH2CO2Et via radical addition Hydrolysis of the esters affords the corresponding carboxylic acids with two more carbons.

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