Chin. J. Org. Chem. ›› 1989, Vol. 9 ›› Issue (4): 321-324. Previous Articles     Next Articles

卟啉化合物的研究 XV: 双卟啉的合成及其与钴离子的络合反应

黄素秋;张克凌;陈敏东;郑穹;夏淑贞;李宝睿   

  1. 武汉大学化学系
  • 发布日期:1989-08-25

Study on porphyrin compounds XV: Synthesis of a diporphyrin and coordination of the diporphyrin with Co(II)

HUANG SUQIU;ZHANG KELING;CHEN MINDONG;ZHENG QIONG;XIA SHUZHEN;LI BAORUI   

  • Published:1989-08-25

I was prepared by the reaction of tris(p-methoxyphenyl)(p-hydroxyphenyl)porphyrin with Br(CH3)2Br, followed by reaction with 1,3-C6H4(OH)2. I reacted with Co(OAc)2 to give Co2L (H4L = I). The kinetics of coordination of I by Co2+ is 1st order, the activation energy was calculated The reaction mechanism is discussed.

Key words: PORPHINE P, REACTION KINETICS, COBALT COMPLEX, COMPLEX REACTION, TRANSITION STATE

CLC Number: