Synthesis of water soluble phthalocyanines

Abstract

Eleven H2O soluble Co, Zn, Cu, Ni, and Al phthalocyanines were synthesized from phthalic anhydride or substituted phthalic anhydride. The substituents on the benzene rings of phthalocyanine are COOH, SO3H, CONH2 et. A successful puritication procedure for H2O soluble phthalocyanines, i.e. fractional extration with varied H2O-EtOH was developed. Their UV/visible fluorescence, some 1H NMR, and mass spectra are presented.

Key words: COBALT COMPOUNDS, PHTHALOCYANINE P, MASS SPECTROGRAPHY, WATER SOLUBILITY, NICKEL COMPOUNDS, PROTON MAGNETIC RESONANCE SPECTROMETRY, ZINC COMPOUNDS, CHROMATOGRAPHY, BACTERICIDAL AGENTS, ALUMINIUM COMPOUNDS

CLC Number:

O627

Cite this article

CHEN FAPU;XU DEYU. Synthesis of water soluble phthalocyanines[J]. Chin. J. Org. Chem., 1990, 10(6): 550-553.

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水溶性酞菁化合物的合成