The study on the reaction of 2-(chloromethyl)furan with lithium trialkylalkynylborates

Chin. J. Org. Chem. ›› 1991, Vol. 11 ›› Issue (3): 322-325. Previous Articles Next Articles

Original Articles

2-氯甲基呋喃与三烷基炔基硼酸盐的反应研究

李南生;陈燕;邓敏智;马益林

中国科学院上海有机化学研究所

发布日期:1991-06-25

The study on the reaction of 2-(chloromethyl)furan with lithium trialkylalkynylborates

LI NANSHENG;CHEN YAN;DENG MINZHI;MA YILING

Published:1991-06-25

Abstract

The reaction of 2-(chloromethyl)furan with lithium trialkylalkynylborate is studied and the configuration of the major furfurylalkene reaction product is determine to be E-form by using 1H NMR NOE technique. The ratio of E and Z isomers of the products is about 80:20. Thus, the reaction with high stereoselectivity may be useful for the preparation of furan derivatives

Key words: FURAN P, INFRARED SPECTROPHOTOMETRY, FURAN P, LITHIUM COMPOUNDS, ORGANIC BORATE, ALKENE P, CHLOROMETHANE P, PROTON MAGNETIC RESONANCE SPECTROMETRY, ALKYNE P, TRIALKYL GROUP

CLC Number:

O627

Cite this article

LI NANSHENG;CHEN YAN;DENG MINZHI;MA YILING. The study on the reaction of 2-(chloromethyl)furan with lithium trialkylalkynylborates[J]. Chin. J. Org. Chem., 1991, 11(3): 322-325.

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2-氯甲基呋喃与三烷基炔基硼酸盐的反应研究

The study on the reaction of 2-(chloromethyl)furan with lithium trialkylalkynylborates

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