Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (6): 622-626. Previous Articles     Next Articles

Original Articles

聚苯乙烯-二苯基膦-铜(Ⅰ)-四氢化硼络合物的制备及其对酰氯的还原

熊桂荣;黄锦霞;张万轩;陈家威   

  1. 武汉市乡镇企业管理局科技处;湖北大学化学系
  • 发布日期:1995-12-25

Preparation of polystyryl diphenyl phosphine copper(Ⅰ) tetrahydroborate and reduction of acyl chloride

XIONG GUIRONG;HUANG JINXIA;ZHANG WANXUAN;CHEN JIAWEI   

  • Published:1995-12-25

A few polystyryl diphenyl copper(Ⅰ) Tetrahydroborate complexes (PDPCT) were prepared using various crosslinking (1%, 2%, 4%, 7%, 8%, 12%) polystyrene beads as supports. Their contents and structures were tested and analyzed, which their behavior reducing benzoyl chlo-ride, cinnamoyl chloride, p-nitrobenzoyl chloride to the corresponding aldehydes or alcohols in the different conditions of temperature, solvent and catalyst and recovering were studied.

Key words: INFRARED SPECTROPHOTOMETRY, HIGH SPEED LIQUID CHROMATOGRAPHY, DIPHENYLPHOSPHINE, POLYSTYRENE, COPPER COMPLEX, REDUCER, ACYL CHLORIDES

CLC Number: