Progress of Water-Soluble Metalloporphyrins in Catalytic Reactions

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (11): 1605-1614. Next Articles

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水溶性金属卟啉应用于催化反应的研究进展

任清刚，周贤太，纪红兵*

(中山大学化学与化学工程学院广州 510275)

收稿日期:2009-11-26 修回日期:2010-03-22 发布日期:2010-05-27
通讯作者: 纪红兵 E-mail:jihb@mail.sysu.edu.cn
基金资助:
国家级.国家自然科学基金

Progress of Water-Soluble Metalloporphyrins in Catalytic Reactions

REN Qing-Gang, ZHOU Xian-Tai, JI Hong-Bing

(School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275)

Received:2009-11-26 Revised:2010-03-22 Published:2010-05-27

Abstract

The latest applications of water-soluble metalloporphyrins as catalysts in catalytic homogeneous or heterogeneous reactions are reviewed, focusing on the catalytic activities of water-soluble metallopor-phyrins-catalyzed oxidation reactions in water or the mixed media of water and organic solvents, including the oxidation of alkanes, epoxidation of alkenes, the oxidation of compounds containing oxygen, sulfur and nitrogen. Water-soluble metalloporphyrins could also be used in other catalytic reactions, such as Suzuki-Miyaura reaction, oxidative coupling reaction, oxidative cleavage of C＝C double bond etc. Water-soluble metalloporphyrins as catalysts will be widely used in catalytic reactions, especially in oxida-tions for its water solubility, effective activity, and under mild conditions.

Key words: water-soluble metalloporphyrin, catalytic oxidation, biomimetic catalysis

Cite this article

REN Qing-Gang, ZHOU Xian-Tai, JI Hong-Bing. Progress of Water-Soluble Metalloporphyrins in Catalytic Reactions[J]. Chin. J. Org. Chem., 2010, 30(11): 1605-1614.

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水溶性金属卟啉应用于催化反应的研究进展

Progress of Water-Soluble Metalloporphyrins in Catalytic Reactions

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