Efficient Synthesis of Alkoxyl Bridging Bisterpyridines

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (12): 1955-1959. Previous Articles Next Articles

Notes

烷氧基桥联双三联吡啶的简洁合成

严晓华¹，杜丽婷²，毕欣²，孙晶²，颜朝国*^,2

(¹扬州职业大学扬州 225009)
(²扬州大学化学化工学院扬州 225002)

收稿日期:2010-01-12 修回日期:2010-06-20 发布日期:2010-07-30
通讯作者: 颜朝国 E-mail:cgyan@yzu.edu.cn
基金资助:
环三聚藜芦烯超分子金属络合物的分子设计，纳米组装和催化反应研究

Efficient Synthesis of Alkoxyl Bridging Bisterpyridines

Yan Xiaohua¹ Du Liting² Bi Xin² Sun Jing² Yan Chaoguo*^,2

(¹Yangzhou Polytechnic College, Yangzhou 225009)
(²College of Chemis-try & Chemical Engineering Yangzhou University, Yangzhou 225002)

Received:2010-01-12 Revised:2010-06-20 Published:2010-07-30

Abstract

A series of novel alkoxy-bridging bis(2,2 :6,2 -terpyridine) ligands were conveniently obtained from one-pot tandem reaction of 2,2 -alkoxy-bridging or 4,4 -alkoxy-bridging dialdehydes with excess of 2-acetylpyridine in sodium hydroxide solution and aqueous ammonia solution, respectively. The structures of the synthetic bisterpyridines were characterized by ¹H NMR, ¹³C NMR and HPMS techniques and further confirmed by determination of single crystal structure of one representative compound.

Key words: tandem reaction, pyridine, terpyridine, aromatic aldehyde, single crystal

Cite this article

YAN Xiao-Hua, DU Li-Ting, BI Xin, SUN Jing, YAN Chao-Guo. Efficient Synthesis of Alkoxyl Bridging Bisterpyridines[J]. Chin. J. Org. Chem., 2010, 30(12): 1955-1959.

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烷氧基桥联双三联吡啶的简洁合成

Efficient Synthesis of Alkoxyl Bridging Bisterpyridines

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