Progress on the Study and Application of Chiral Oxazaborolidines

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (01): 22-38. Previous Articles Next Articles

Reviews

手性噁唑硼烷的研究进展及其应用

汪泳¹，李文红²，曹云涛¹，李媛*^,1

(¹河北师范大学化学与材料科学学院石家庄 050016)
(²河北工业职业技术学院环境与化学工程系石家庄 050091)

收稿日期:2009-10-19 修回日期:2010-05-23 发布日期:2010-06-18
通讯作者: 李媛 E-mail:yuanli@mail.hebtu.edu.cn
基金资助:
国家级.国家自然科学基金

Progress on the Study and Application of Chiral Oxazaborolidines

Wang Yong¹ Li Wenhong² Cao Yuntao¹ Li Yuan*^,1

(¹College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016)
(²Environment and Chemical Engineering, Heibei College of Industry and Technology, Shijiazhuang 050091)

Received:2009-10-19 Revised:2010-05-23 Published:2010-06-18

Abstract

Chiral oxazaborolidines are very important catalysts for asymmetric reduction of ketone, cyclic meso-imides and imines as well as Mukaiyama aldol reaction and enantioselective Diels-Alder addition with excellent yield and enantioselectivity. Progress on the study of chiral oxazaborolidines and their application in synthesizing natural or non-natural products and biological active compounds including VB₁₂are reviewed.

Key words: chiral oxazaborolidine, enantioselective synthesis, asymmetric reduction, asymmetric Diels-Alder reaction, asymmetric Mukaiyama aldol reaction

Cite this article

WANG Yong, LI Wen-Hong, CAO Yun-Tao, LI Yuan. Progress on the Study and Application of Chiral Oxazaborolidines[J]. Chin. J. Org. Chem., 2011, 31(01): 22-38.

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手性噁唑硼烷的研究进展及其应用

Progress on the Study and Application of Chiral Oxazaborolidines

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