Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (03): 401-414. Previous Articles     Next Articles

Reports

基于C=O…HN分子间氢键的超分子液晶研究进展

白炳莲*,1,2,欧海峰3,冉霞1,张艳1,王海涛1,李敏*,1   

  1. (1吉林大学汽车材料教育部重点实验室 吉林大学材料科学与工程学院 长春 130012)
    (2吉林大学物理学院 长春 130023)
    (3河南工业大学理学院 郑州 450052)
  • 收稿日期:2010-03-20 修回日期:2010-07-25 发布日期:2010-09-28
  • 通讯作者: 白炳莲 E-mail:baibinglian@jlu.edu.cn

Supramolecular Liquid Crystals Based on C=O…HN Intermolecular Hydrogen Bonding

Bai Binglian*,1,2 Ou Haifeng3 Ran Xia1 Zhang Yan1 Wang Haitao1 Li Min*,1   

  1. (1 Key Laboratory for Automobile Materials (JLU), Ministry of Education, Institute of Materials Science and Engineering, Jilin University, Changchun 130012)
    (2 College of Physics, Jilin University, Changchun 130023)
    (3 College of Science, Henan University of Technology, Zhengzhou 450052)
  • Received:2010-03-20 Revised:2010-07-25 Published:2010-09-28
  • Contact: bai binglian E-mail:baibinglian@jlu.edu.cn

The C=O…HN intermolecular hydrogen bonding is very important in building highly functional soft materials because it can form ordered structures of defined geometry and stability through self-assembly. Molecular shape is an important factor in design low-weight molecular thermotropic liquid crystals, and it has a strong impact on mesophases. This paper presents a brief review on the molecular shape-property relationships and the recent progress in supramolecules liquid crystals of discotic and tapered molecules based on C=O…HN intermolecular hydrogen bonding, which might be the guidance for designing novel liquid crystals.

Key words: intermolecular hydrogen bonding, discotic molecule, tapered molecule, molecular shap