Frustrated Lewis Pairs: A New Strategy for Metal-Free Catalytic Hy-drogenation

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (9): 1369-1376. Previous Articles Next Articles

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失配的Lewis对: 非金属催化氢化的新策略

王平安*，孙晓莉，高鹏

(第四军医大学药学系化学教研室西安 710032)

收稿日期:2010-12-13 修回日期:2011-01-21 发布日期:2011-02-18
通讯作者: 王平安 E-mail:ping_an1718@yahoo.com.cn

Frustrated Lewis Pairs: A New Strategy for Metal-Free Catalytic Hy-drogenation

WANG Ping-An, SUN Xiao-Li, GAO Peng

(Department of Chemistry, School of Pharmacy, Fourth Military Medical University, Xian 710032)

Received:2010-12-13 Revised:2011-01-21 Published:2011-02-18

“Frustrated Lewis Pairs” (FLPs) as a new concept in organic chemistry was used in metal-free activation of some small molecules such as H₂, CO₂ and NH₃, and its researches and applications are very attractive to chemists. The good to excellent results were obtained in catalytic hydrogenation of aldehydes, enamines, imines, nitriles and CO₂ by using various FLPs as catalysts and H₂ as hydrogen source. The chiral FLPs also demonstrate good enantioselectivities in metal-free catalytic hydrogenation of imines, and the enantiomeric excess of the corresponding amines is up to 83%. This review describes the development of FLPs for metal-free catalytic hydrogenation in recent years.

Key words: frustrated Lewis pairs, activation of molecular hydrogen, metal-free catalytic hydrogenation

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WANG Ping-An, SUN Xiao-Li, GAO Peng. Frustrated Lewis Pairs: A New Strategy for Metal-Free Catalytic Hy-drogenation[J]. Chin. J. Org. Chem., 2011, 31(9): 1369-1376.

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失配的Lewis对: 非金属催化氢化的新策略

Frustrated Lewis Pairs: A New Strategy for Metal-Free Catalytic Hy-drogenation

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