Synthesis of Novel Organic Nonlinear Optical Chromophores and the Enhancement of Electro-optic Activity of the Additional Donors

doi:10.6023/cjoc201209020

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (03): 530-534.DOI: 10.6023/cjoc201209020 Previous Articles Next Articles

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新型二阶非线性光学生色团的合成及辅助给体对分子性能的影响研究

游英才^a, 唐先忠^a,b, 唐翔^a,b, 贾鲲鹏^b, 王洋^a, 李昱树^a, 张煜^a

a 电子科技大学电子薄膜与集成器件国家重点实验室成都 610054;
b 中国人民解放军63916部队北京 100000

收稿日期:2012-09-13 修回日期:2012-12-12 发布日期:2012-12-18
通讯作者: 唐先忠 E-mail:txzhong@uestc.edu.cn
基金资助:
国家自然科学基金(No. 60771044)资助项目

Synthesis of Novel Organic Nonlinear Optical Chromophores and the Enhancement of Electro-optic Activity of the Additional Donors

You Yingcai^a, Tang Xianzhong^a,b, Tang Xiang^a,b, Jia Kunpeng^b, Wang Yang^a, Li Yushu^a, Zhang Yu^a

a State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054;
b People’s Liberation Army 63916 Troops, Beijing 100000

Received:2012-09-13 Revised:2012-12-12 Published:2012-12-18
Supported by:
Project supported by the National Natural Science Foundation of China (No. 60771044).

1. Synthesis of Novel Organic Nonlinear Optical Chromophores and the Enhancement of Electro-optic Activity of the Additional Donors.PDF(267KB)

Abstract

In order to study the impact of different additional donors on molecular thermal decomposition temperature (T_d) value of the chromophores as well as the second polarization (μ_gβ) value. Three novel materials EFC-OH, EFC-OBu and EFC- OBe were synthesized by attaching additional donors to the benzene ring based on the reported 2-[{4-(4-diethylamino)sty- reneyl}-3-cyano-5,5-dimethyl-5H-furan-2-ylidene]malononitrile (DCDHF-2-V). The three chromophores were characterized by ¹H NMR, ¹³C NHR, FT-IR and elemental analysis. The T_d value was determined by TGA testing, and the result showed that three molecules had a good thermal performance. EFC-OBe processing a T_d of 278.6 ℃ showed the best among these molecules. The hyperpolarizability was measured and calculated by solvatochromism method. EFC-OBe still showed the best μ_gβ value of 4.7149×10^-44 esu. Comparing to the DCDHF-2-V without additional donors on T_d value and μ_gβ value, additional donors had little effect on T_d value while achieved an improvement of one order of magnitude in μ_gβ values, which indicates that the molecules can work in high temperature and performance better in optics.

Key words: nonlinear optics, additional donor, thermogravimetic analysis (TGA), solvatochromism

Cite this article

You Yingcai, Tang Xianzhong, Tang Xiang, Jia Kunpeng, Wang Yang, Li Yushu, Zhang Yu. Synthesis of Novel Organic Nonlinear Optical Chromophores and the Enhancement of Electro-optic Activity of the Additional Donors[J]. Chin. J. Org. Chem., 2013, 33(03): 530-534.

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新型二阶非线性光学生色团的合成及辅助给体对分子性能的影响研究

Synthesis of Novel Organic Nonlinear Optical Chromophores and the Enhancement of Electro-optic Activity of the Additional Donors

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