Synthesis of Novel Trichloride Indenyl Zirconium Complexes with Pendant Pyridine Moiety

doi:10.6023/cjoc201310032

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (1): 197-203.DOI: 10.6023/cjoc201310032 Previous Articles Next Articles

新型侧链含吡啶的三氯一茚锆络合物的合成

张延路, 马海燕, 黄吉玲

华东理工大学金属有机化学实验室上海 200237

收稿日期:2013-10-21 修回日期:2013-12-05 发布日期:2013-12-19
通讯作者: 黄吉玲 E-mail:jlhuang@ecust.edu.cn
基金资助:
国家自然科学基金（No. 20372022）资助项目.

Synthesis of Novel Trichloride Indenyl Zirconium Complexes with Pendant Pyridine Moiety

Zhang Yanlu, Ma Haiyan, Huang Jiling

Laboratory of Organometallics Chemistry, East China University of Science and Technology, Shanghai 200237

Received:2013-10-21 Revised:2013-12-05 Published:2013-12-19
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20372022).

1. Synthesis of Novel Trichloride Indenyl Zirconium Complexes with Pendant Pyridine Moiety.PDF(103KB)

Abstract

It is always difficult to synthesize half-sandwich trichloride cyclopentadienyl (indenyl) zirconium complexes due to accompanying the formation of sandwich metallocene (indenyl) zirconium complexes. In this paper, a series of novel trichloride indenyl zirconium complexes, [Ind-Bridge-Py]ZrCl₃·THF_x (CN1～CN3), bearing pendant pyridine moiety with chelating ring structure, were synthesized selectively by directly reacting lithium salts of substituted indenyl with ZrCl₄·2THF, and no di-indenyl zirconium complexes were formed. Compared with conventional methods of synthesizing half-sandwich indenyl complexes, the synthetic method of these kinds of trichloride indenyl zirconium complexes with pendant pyridine moiety has the advantages of easy operation, single product, easy separation and high yield. The X-ray of CN2 [Bridge: C(Me, Et)CH₂] shows that zirconium is coordinated with N atom and also with one O atom from THF. Another molecule of THF in the crystal is free and not coordinated with zirconium.

Key words: pyridine, trichloride indenyl zirconium, coordination, tetrahydrofuran

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Zhang Yanlu, Ma Haiyan, Huang Jiling. Synthesis of Novel Trichloride Indenyl Zirconium Complexes with Pendant Pyridine Moiety[J]. Chin. J. Org. Chem., 2014, 34(1): 197-203.

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新型侧链含吡啶的三氯一茚锆络合物的合成

Synthesis of Novel Trichloride Indenyl Zirconium Complexes with Pendant Pyridine Moiety

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