Extractive Desulfurization of Fuel Oil with Metal-Based Hyamine Ionic Liquids

doi:10.6023/cjoc201311004

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (7): 1462-1468.DOI: 10.6023/cjoc201311004 Previous Articles Next Articles

Notes

季铵盐类金属基离子液体对燃料油萃取脱硫性能研究

赵地顺^a, 李俊盼^a, 张娟^a, 任培兵^a,b, 葛京京^a, 任腾杰^a, 崔云^a

a 河北科技大学化学与制药工程学院石家庄 050018;
b 石家庄焦化集团有限责任公司石家庄 050031

收稿日期:2013-11-04 修回日期:2014-01-26 发布日期:2014-03-12
通讯作者: 赵地顺 E-mail:zhao_dsh@hebust.edu.cn
基金资助:
国家自然科学基金（Nos.20576026，21106032）资助项目.

Extractive Desulfurization of Fuel Oil with Metal-Based Hyamine Ionic Liquids

Zhao Dishun^a, Li Junpan^a, Zhang Juan^a, Ren Peibing^a,b, Ge Jingjing^a, Ren Tengjie^a, Cui Yun^a

a College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018;
b Shijiazhuang Coking and Chemical Group Co., Ltd., Shijiazhuang 050031

Received:2013-11-04 Revised:2014-01-26 Published:2014-03-12
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 20576026, 21106032).

1. Extractive Desulfurization of Fuel Oil with Metal-Based Hyamine Ionic Liquids.PDF(45KB)

Abstract

Five metal-based hyamine ionic liquids (CPL-TBAB)/MCl_n (M=Ni, Cu, Co, Zn, Fe) were synthesized and investigated in extractive desulfurization of model oil. The result indicated that (CPL-TBAB)/CuCl₂·2H₂O was superior to other ionic liquids for the extraction desulfurization. The removal ratio of dibenzothiophene (DBT) can be up to 97.10% under the optimal reaction conditions having the suitable molar ratio of CPL-TBAB to CuCl₂·2H₂O being 1:0.8 and V_IL/V_OIL being 1:1 at room temperature and atmosphere. The extraction ability of ionic liquid decreases only slightly after 6 cycles of reuse. (CPL-TBAB)/0.8CuCl₂·2H₂O showed an excellent extraction ability for different sulfur compounds model oil and real diesel. The single extractive desulfurization removal ratio of real diesel was 75.59%. These results demonstrate that this metal-based ionic liquid is a promising extractive desulfurization agent.

Key words: metal-based ionic liquid, diesel, extract, desulfurization

Cite this article

Zhao Dishun, Li Junpan, Zhang Juan, Ren Peibing, Ge Jingjing, Ren Tengjie, Cui Yun. Extractive Desulfurization of Fuel Oil with Metal-Based Hyamine Ionic Liquids[J]. Chin. J. Org. Chem., 2014, 34(7): 1462-1468.

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季铵盐类金属基离子液体对燃料油萃取脱硫性能研究

Extractive Desulfurization of Fuel Oil with Metal-Based Hyamine Ionic Liquids

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