Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (10): 1941-1957.DOI: 10.6023/cjoc201405003 Previous Articles     Next Articles

Reviews

单质碘促进的有机反应研究进展

赵巾巾, 高文超, 常宏宏, 李兴, 刘强, 魏文珑   

  1. 太原理工大学化学化工学院生物与制药工程系 太原 030024
  • 收稿日期:2014-05-04 修回日期:2014-06-02 发布日期:2014-06-23
  • 通讯作者: 高文超, 常宏宏 E-mail:gaowenchao@tyut.edu.cn;changhonghong@tyut.edu.cn
  • 基金资助:

    山西省自然科学基金(Nos. 2012021007-2,2011011010-2)、山西省高等学校科技创新基金(No. 20120006)、太原理工大学引进人才启动经费(No. tyut-rc201307a)资助项目.

Recent Advances in Iodine-Mediated Organic Reactions

Zhao Jinjin, Gao Wenchao, Chang Honghong, Li Xing, Liu Qiang, Wei Wenlong   

  1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024
  • Received:2014-05-04 Revised:2014-06-02 Published:2014-06-23
  • Supported by:

    Project supported by the Natural Science Foundation of Shanxi Province (Nos. 2012021007-2, 2011011010-2), the Scientific and Technologial Innovation Programs of Higher Education Institutions in Shanxi Province (No. 20120006), and the Qualified Personnel Foundation of Taiyuan University of Technology (No. tyut-rc201307a).

As one of simplest chemical reagents, iodine has promoted diverse organic transformations, which have attracted much attention in recent years. The present review summarizes three basic chemical features of iodine in organic synthesis: the oxidative reactivity, the acidic reactivity and the electrophilic reactivity, along with the introduction of corresponding representative examples. Furthermore, the iodine-catalyzed reactions involed in the synthesis of heterocycles, organic coupling reactions, the C-H functionalization, and other applications are also presented in this review.

Key words: iodine, oxidation, acidity, electrophilic cyclisation, heterocycle syntheses, organocatalysis