Synthesis of Nanoporous Polystyrene Microspheres for Efficient Incorporation of L-Menthol

doi:10.6023/cjoc201410011

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (2): 390-395.DOI: 10.6023/cjoc201410011 Previous Articles Next Articles

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纳米多孔聚苯乙烯微球的合成及其用于负载L-薄荷醇

刘绍华^a, 王希庆^b, 黄天辉^a, 邓勇辉^b, 吴彦^a, 冯守爱^a, 白家峰^a, 田兆福^a

a 广西中烟工业有限责任公司南宁 530001;
b 复旦大学化学系上海 200433

收稿日期:2014-10-09 修回日期:2014-11-03 发布日期:2014-11-20
通讯作者: 邓勇辉 E-mail:yhdeng@fudan.edu.cn

Synthesis of Nanoporous Polystyrene Microspheres for Efficient Incorporation of L-Menthol

Liu Shaohua^a, Wang Xiqing^b, Huang Tianhui^a, Deng Yonghui^b, Wu Yan^a, Feng Shou'ai^a, Bai Jiafeng^a, Tian Zhaofu^a

a China Tobacco Guangxi Industrial Co., Ltd., Nanning 530001;
b Department of Chemistry, Fudan University, Shanghai 200433

Received:2014-10-09 Revised:2014-11-03 Published:2014-11-20

1. Synthesis of Nanoporous Polystyrene Microspheres for Efficient Incorporation of L-Menthol.PDF(222KB)

Abstract

In this study, cross-linked polystyrene microspheres (PS) with high porosity were synthesized via a suspension polymerization method. A series of menthol@polystyrene microsphere composites were synthesized via a novel "in-pore crystallization" strategy by employing porous PS microspheres as the carrier. The release behavior of menthol under different temperature was studied by a hot-air sweeping method, and it was found to be fitted with the law of biphase kinetics. Compared to the samples obtained via mechanically blending, the present supported composites display a controlled release of menthol in a rather broad temperature range (30～80 ℃). This kind of new preparation technology is expected to be useful for designing novel high-performance menthol-based products.

Key words: suspension polymerization, porous polystyrene, menthol, in-pore crystallization, controlled release

Cite this article

Liu Shaohua, Wang Xiqing, Huang Tianhui, Deng Yonghui, Wu Yan, Feng Shou'ai, Bai Jiafeng, Tian Zhaofu. Synthesis of Nanoporous Polystyrene Microspheres for Efficient Incorporation of L-Menthol[J]. Chin. J. Org. Chem., 2015, 35(2): 390-395.

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纳米多孔聚苯乙烯微球的合成及其用于负载L-薄荷醇

Synthesis of Nanoporous Polystyrene Microspheres for Efficient Incorporation of L-Menthol

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