Tetraphenylpyrazine-Based Luminogens with Aggregation-Enhanced Emission Characteristics: Preparation and Property

doi:10.6023/cjoc201602020

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (6): 1316-1324.DOI: 10.6023/cjoc201602020 Previous Articles Next Articles

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具有聚集荧光增强效应的四苯基吡嗪类衍生物的制备和性能研究 2017-2018 Awarded

潘凌翔^a, 罗文文^a, 陈明^b, 刘峻恺^a, 徐露^a, 胡蓉蓉^a, 赵祖金^a, 秦安军^a, 唐本忠^a,b

a 华南理工大学发光材料与器件国家重点实验室广州 510640;
b 香港科技大学化学系国家人体组织功能重建工程技术研究中心香港分中心香港九龙清水湾

收稿日期:2016-02-22 修回日期:2016-04-03 发布日期:2016-04-07
通讯作者: 秦安军, 唐本忠 E-mail:msqinaj@scut.edu.cn;tangbenz@ust.hk
基金资助:
国家自然科学基金(No.21525417)、国家重点基础研究发展规划(973计划)(No.2013CB834702)、中组部青年拔尖人才支持计划和广东省引进创新科研团队(No.201101C0105067115)资助项目.

Tetraphenylpyrazine-Based Luminogens with Aggregation-Enhanced Emission Characteristics: Preparation and Property

Pan Lingxiang^a, Luo Wenwen^a, Chen Ming^b, Liu Junkai^a, Xu Lu^a, Hu Rongrong^a, Zhao Zujin^a, Qin Anjun^a, Tang BenZhong^a,b

aState Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640;
b Hong Kong Branch of National Engineering Research Center for Tissue Restoration & Reconstruction, Department of Chemistry, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong

Received:2016-02-22 Revised:2016-04-03 Published:2016-04-07
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21525417), the National Key Basic Research Program of China (973 Program) (No. 2013CB834702), and the National Program for Support of Top-Notch Young Professionals and the Guangdong Innovative Research Team Program (No. 201101C0105067115).

1. Tetraphenylpyrazine-Based Luminogens with Aggregation-Enhanced Emission Characteristics: Preparation and Property.PDF(1809KB)

Abstract

The research on aggregation-induced emission (AIE) has been a hot topic in the fields of photo-physics and luminescent materials. Design and synthesis of new AIE-active luminogens (AIEgens) will further promote the development of this area. Based on our developed new AIEgen of tetraphenylpyrazine (TPP), in this paper, we further enriched its family by covalently attaching thiophene unit on TPP core, and prepared three AIEgens of TPP-T, TPP-2T and T-TPP-T. Their structure-property relationship was studied in detail. The results showed that TPP-T, TPP-2T and T-TPP-T feature the aggregation-enhanced emission (AEE) characteristics. Their powders emit at 418, 437 and 436 nm with absolute fluorescence quantum yields of 26.8, 29.0 and 30.9%, respectively, which makes them promising to be used as emitting layer in fabrication of organic light-emitting diodes in combination with their excellent thermal stability.

Key words: tetraphenylpyrazine, aggregation-enhanced emission (AEE), structure-property relationship

Cite this article

Pan Lingxiang, Luo Wenwen, Chen Ming, Liu Junkai, Xu Lu, Hu Rongrong, Zhao Zujin, Qin Anjun, Tang BenZhong. Tetraphenylpyrazine-Based Luminogens with Aggregation-Enhanced Emission Characteristics: Preparation and Property[J]. Chin. J. Org. Chem., 2016, 36(6): 1316-1324.

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具有聚集荧光增强效应的四苯基吡嗪类衍生物的制备和性能研究 2017-2018 Awarded

Tetraphenylpyrazine-Based Luminogens with Aggregation-Enhanced Emission Characteristics: Preparation and Property

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