Copolymerization of Ethylene/Polar Monomer Catalyzed by Phosphinoarenesulfonate (PO) Metal Catalysts and the Catalytic Mechanism

doi:10.6023/cjoc201603048

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (10): 2344-2352.DOI: 10.6023/cjoc201603048 Previous Articles Next Articles

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膦基苯磺酸(PO)金属配合物催化乙烯与极性单体的共聚反应及其机理研究进展

苏碧云^a, 郏佩瑜^b, 王彦昭^a, 李亚宁^a, 黄鹤^a, 李谦定^a

a 西安石油大学化学化工学院西安 710065;
b 宁波激智科技股份有限公司宁波 315100

收稿日期:2016-03-30 修回日期:2016-05-11 发布日期:2016-06-08
通讯作者: 苏碧云,E-mail:subiyun@xsyu.edu.cn E-mail:subiyun@xsyu.edu.cn
基金资助:
陕西省教育厅专项科研基金（No.12JK0620）和陕西省科学技术研究发展计划（No.2013 KJXX-33）资助项目.

Copolymerization of Ethylene/Polar Monomer Catalyzed by Phosphinoarenesulfonate (PO) Metal Catalysts and the Catalytic Mechanism

Su Biyun^a, Jia Peiyu^b, Wang Yanzhao^a, Li Yaning^a, Huang He^a, Li Qianding^a

a College of Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an 710065;
b Ningbo Exciton Technology, Co., Ltd., Ningbo 315100

Received:2016-03-30 Revised:2016-05-11 Published:2016-06-08
Supported by:
ProjectProject of Shaanxi Education Department (No.12JK0620) and the Science and Technology Research Program of Shaanxi Province (No.2013 KJXX-33).

The metal catalysts based on phosphinoarenesulfonate (PO) ligand display interesting olefin polymerization prop-erties, which not only polymerize ethylene to linear polyethylene, but also copolymerize ethylene with polar vinyl monomers or CO to functional linear copolymers. The structural features of PO ligand and the novel polymerization reactions initiated by (PO)Pd(Ⅱ) complexes are assumed. Then the application of (PO)Ni(Ⅱ) catalysts in the copolymerization of ethylene with polar monomers, as well as the rare catalytic properties of Pd(Ⅱ), Ru(Ⅳ) catalysts based on phosphine-bis(arenesulfonate) (OPO) ligands are reviewed. At last, the influence of PO ligand structural features such as symmetry, flexibility, steric effect in axial direction, as well as the pure electronic effect on the insertion and polymerization reactivity of PO metal catalyst are explored, at the same time, the catalytic reaction mechanism is also studied.

Key words: olefin/polar monomer copolymerization, phosphinoarenesulfonate ligand, Pd(Ⅱ), Ni(Ⅱ), Ru(IV) catalyst, catalytic mechanism

Cite this article

Su Biyun, Jia Peiyu, Wang Yanzhao, Li Yaning, Huang He, Li Qianding. Copolymerization of Ethylene/Polar Monomer Catalyzed by Phosphinoarenesulfonate (PO) Metal Catalysts and the Catalytic Mechanism[J]. Chin. J. Org. Chem., 2016, 36(10): 2344-2352.

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膦基苯磺酸(PO)金属配合物催化乙烯与极性单体的共聚反应及其机理研究进展

Copolymerization of Ethylene/Polar Monomer Catalyzed by Phosphinoarenesulfonate (PO) Metal Catalysts and the Catalytic Mechanism

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