Highly Selective Naked-Eye and Fluorescence Probe for Cu2+ Based on Carbazole Schiff-Base

doi:10.6023/cjoc201611014

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (4): 896-901.DOI: 10.6023/cjoc201611014 Previous Articles Next Articles

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基于咔唑-席夫碱的高选择性裸眼和荧光识别Cu²⁺的探针

李英俊^a, 李继阳^a, 许永廷^a, 靳焜^b, 曹欣^a

a. 辽宁师范大学化学化工学院大连 116029;
b. 大连理工大学精细化工国家重点实验室大连 116012

收稿日期:2016-11-12 修回日期:2016-12-26 发布日期:2017-01-17
通讯作者: 李英俊 E-mail:chemlab.lnnu@163.com
基金资助:
辽宁省自然科学基金（No.20102126）资助项目.

Highly Selective Naked-Eye and Fluorescence Probe for Cu²⁺ Based on Carbazole Schiff-Base

Li Yingjun^a, Li Jiyang^a, Xu Yongting^a, Jin Kun^b, Cao Xin^a

a. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029;
b. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Received:2016-11-12 Revised:2016-12-26 Published:2017-01-17
Contact: 10.6023/cjoc201611014 E-mail:chemlab.lnnu@163.com
Supported by:
Project supported by the Natural Science Foundation of Liaoning Province (No. 20102126).

1. Highly Selective Naked-Eye and Fluorescence Probe for Cu²⁺ Based on Carbazole Schiff-Base.PDF(215KB)

Abstract

A new fluorescence probe L based on carbazole Schiff-base for Cu²⁺ was synthesized. The recognition ability of probe L to metal ions was investigated by UV-Vis and fluorescence spectra. The experimental results showed that the probe L in CH₃CN displayed a distinct color change from yellow to colorless upon the addition of Cu²⁺, which can be directly detected by the naked eye for Cu²⁺. The fluorescence spectra showed that the probe L had high selective and sensitive recognition toward Cu²⁺ in CH₃CN, the fluorescence intensity was increased with the increase of Cu²⁺ concentration, and it was not affected by other metal ions. The association constant between the probe L and Cu²⁺ was detected to be 1.38×10⁴L/mol and the corresponding detection limit was calculated to be 2.34×10^-7 mol/L. The detection limit of L for Cu²⁺ was far lower than the maximum allowable level of the WHO limit (20 mmol/L) for drinking water. The results indicate that the probe L should be applicable to the research on the environmental applications associated with Cu²⁺.

Key words: carbazole, Schiff base, naked-eye recognition, Cu²⁺ fluorescence probe

Cite this article

Li Yingjun, Li Jiyang, Xu Yongting, Jin Kun, Cao Xin. Highly Selective Naked-Eye and Fluorescence Probe for Cu²⁺ Based on Carbazole Schiff-Base[J]. Chin. J. Org. Chem., 2017, 37(4): 896-901.

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基于咔唑-席夫碱的高选择性裸眼和荧光识别Cu²⁺的探针

Highly Selective Naked-Eye and Fluorescence Probe for Cu²⁺ Based on Carbazole Schiff-Base

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基于咔唑-席夫碱的高选择性裸眼和荧光识别Cu2+的探针