Iron Catalyzed Oxidative Hydroarylation, Methylarylation, and Diarylation of Vinylarenes to Generate Unsymmetrical 1,1-Diarylalkanes

doi:10.6023/cjoc201702036

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (5): 1160-1164.DOI: 10.6023/cjoc201702036 Previous Articles Next Articles

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铁催化烯基芳烃的氢芳基化、甲基芳基化和二芳基化制备非对称1，1-二芳基烷烃的反应（英文）

Kaki Raveendra Babu^a,b, 陈绍维^a,b, 李亚军^b, 鲍红丽^b

a 福州大学化学化工学院福州 350108;
b 中国科学院福建物质结构研究所煤制乙二醇及相关技术重点实验室福州 350002

收稿日期:2017-02-25 修回日期:2017-03-25 发布日期:2017-03-31
通讯作者: 鲍红丽 E-mail:hlbao@fjirsm.ac.cn
基金资助:
国家自然科学基金（Nos.21402200，21502191，21672213，21232001），中国科学院战略先导科技专项（No.XDB20000000）资助项目.

Iron Catalyzed Oxidative Hydroarylation, Methylarylation, and Diarylation of Vinylarenes to Generate Unsymmetrical 1,1-Diarylalkanes

Babu Kaki Raveendra^a,b, Chen Shaowei^a,b, Li Yajun^b, Bao Hongli^b

a College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108;
b Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou 350002

Received:2017-02-25 Revised:2017-03-25 Published:2017-03-31
Contact: 10.6023/cjoc201702036 E-mail:hlbao@fjirsm.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21402200, 21502191, 21672213, 21232001), the Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB20000000).

1. Iron Catalyzed Oxidative Hydroarylation, Methylarylation, and Diarylation of Vinylarenes to Generate Unsymmetrical 1,1-Diarylalkanes.PDF(933KB)

Abstract

A novel iron catalyzed hydroarylation, methylarylation, and diarylation of styrenes to form unsymmetrical 1,1-diarylalkanes with electron rich anisole and 1,3,5-trimethoxybenzene under mild conditions have been developed. Benzoyl peroxide is used as an oxidant for hydroarylation, whereas in the case of methylarylation and diarylation the oxidant tert-butyl peracetate is used.

Key words: hydroarylation, methylarylation, diarylation, vinylarenes, 1,1-diarylalkanes

Cite this article

Babu Kaki Raveendra, Chen Shaowei, Li Yajun, Bao Hongli. Iron Catalyzed Oxidative Hydroarylation, Methylarylation, and Diarylation of Vinylarenes to Generate Unsymmetrical 1,1-Diarylalkanes[J]. Chin. J. Org. Chem., 2017, 37(5): 1160-1164.

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铁催化烯基芳烃的氢芳基化、甲基芳基化和二芳基化制备非对称1，1-二芳基烷烃的反应（英文）

Iron Catalyzed Oxidative Hydroarylation, Methylarylation, and Diarylation of Vinylarenes to Generate Unsymmetrical 1,1-Diarylalkanes

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