Preparation of D-Sorbitol by Catalytic Hydrogenation of D-Glucose with Semi Sandwich Iridium Catalyst

doi:10.6023/cjoc201708001

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (12): 3170-3176.DOI: 10.6023/cjoc201708001 Previous Articles Next Articles

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半三明治型铱催化剂催化氢化葡萄糖制备山梨糖醇

龚宝祥, 严龙, 陈蒙远, 邓晋, 傅尧

中国科学技术大学化学与材料科学学院安徽省生物质洁净能源重点实验室 230026

收稿日期:2017-08-01 修回日期:2017-08-31 发布日期:2017-09-15
通讯作者: 邓晋, 傅尧 E-mail:dengjin@ustc.edu.cn;fuyao@ustc.edu.cn
基金资助:
国家自然科学基金（Nos.21572212，21402181，21325208）、中国科学院项目基金（Nos.XDB20000000，YZ201563）、中央高校基础研究经费、教育部长江学者和创新团队发展计划、安徽省科技攻关计划（No.1604a0702027）资助项目.

Preparation of D-Sorbitol by Catalytic Hydrogenation of D-Glucose with Semi Sandwich Iridium Catalyst

Gong Baoxiang, Yan Long, Chen Mengyuan, Deng Jin, Fu Yao

Anhui Province Key Laboratory of Biomass Clean Energy, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026

Received:2017-08-01 Revised:2017-08-31 Published:2017-09-15
Contact: 10.6023/cjoc201708001 E-mail:dengjin@ustc.edu.cn;fuyao@ustc.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21572212, 21402181, 21325208), the Science Foundation of the Chinese Academy of Sciences (Nos. XDB20000000, YZ201563), the Fundamental Research Funds for the Central Universities, the Program for Changjiang Scholars and Innovative Research Team in University of the Ministry of Education of China, the Key Technologies R&D Programme of Anhui Province (No. 1604a0702027).

1. Preparation of D-Sorbitol by Catalytic Hydrogenation of D-Glucose with Semi Sandwich Iridium Catalyst.PDF(945KB)

Abstract

[Cp^*Ir-(di-OH-bpy)(OH₂)] [SO₄] (di-OH-bpy=4,4'-dihydroxyl-2,2'-bipyridine) exhibited high catalytic performance during the hydrogenation of D-glucose to D-sorbitol. Using formic acid as hydrogen source led to an unsatisfactory D-sorbitol selectivity. The ring-opening hydrogenation of glucose was efficiently achieved by hydrogen. Under optimal conditions, D-sorbitol could be obtained in 96% yield. The effect of different ligands in iridium catalyst on hydrogenation was also investigated. A speculated mechanism was proposed to illustrate the detailed process of D-glucose hydrogenation to produce sorbitol. The catalytic system has the merits of relatively mild reaction conditions and high product selectivity, which provides an effective method for the catalytic hydrogenation of other biomass-based platform chemicals.

Key words: glucose, sorbitol, Cp^*Ir, homogeneous hydrogenation, bipyridine ligand

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Gong Baoxiang, Yan Long, Chen Mengyuan, Deng Jin, Fu Yao. Preparation of D-Sorbitol by Catalytic Hydrogenation of D-Glucose with Semi Sandwich Iridium Catalyst[J]. Chin. J. Org. Chem., 2017, 37(12): 3170-3176.

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半三明治型铱催化剂催化氢化葡萄糖制备山梨糖醇

Preparation of D-Sorbitol by Catalytic Hydrogenation of D-Glucose with Semi Sandwich Iridium Catalyst

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