Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (1): 200-207.DOI: 10.6023/cjoc201708063 Previous Articles     Next Articles

Special Issue: 庆祝吴养洁院士九十华诞专辑 碳氢活化合辑2018-2019

Articles

吡啶乙醇类双[N,O]环钯配合物在Fujiwara-Moritani反应中的高效催化应用

李亚波, 申振, 黄萌萌, 张建业, Jung Keun Kim, 吴养洁   

  1. 郑州大学化学与分子工程学院 河南省化学生物与有机化学重点实验室河南省高等学校应用化学重点开放实验室 郑州 450052
  • 收稿日期:2017-08-30 修回日期:2017-09-19 发布日期:2017-09-26
  • 通讯作者: 黄萌萌, Jung Keun Kim E-mail:kim@zzu.edu.cn;hmm@zzu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21172200,21302172)资助项目.

Highly Catalytic Activity of Bis(alkoxo)palladium Complexes for Fujiwara-Moritani Reaction

Li Yabo, Shen Zhen, Huang Mengmeng, Zhang Jianye, Kim Jung Keun, Wu Yangjie   

  1. College of Chemistry and Molecular Engineering, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052
  • Received:2017-08-30 Revised:2017-09-19 Published:2017-09-26
  • Contact: 10.6023/cjoc201708063 E-mail:kim@zzu.edu.cn;hmm@zzu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21172200, 21302172).

A series of bis(alkoxo)palladium complexes (2 mol%) based on pyridine-containing alcohol ligand were tested for Fujiwara-Moritani reaction of thiophenes/furans with various olefins. The desired products were isolated in moderate to excellent yields under mild conditions. A possible concerted metalation-deprotonation (CMD) pathway for this transformation was proved by control experiments and ESI(+)-MS analysis.

Key words: bis(alkoxo)palladium complex, Fujiwara-Moritani reaction, CMD pathway, pyridine-containing alcohol ligand