Ultrasonic-Assisted Synthesis of 2-Sulfonyl Nitrogen Heterocyclic Compounds

doi:10.6023/cjoc201707029

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (2): 492-497.DOI: 10.6023/cjoc201707029 Previous Articles Next Articles

Notes

超声促进2-磺酰基氮杂环化合物的合成研究

兰立新, 肖洁, 肖怀秋, 易卫国

湖南化工职业技术学院株洲 412004

收稿日期:2017-07-25 修回日期:2017-10-16 发布日期:2017-10-31
通讯作者: 易卫国 E-mail:wgyi_hunan@126.com
基金资助:
湖南省教育厅科学研究（No.15C0464）资助项目.

Ultrasonic-Assisted Synthesis of 2-Sulfonyl Nitrogen Heterocyclic Compounds

Lan Lixin, Xiao Jie, Xiao Huaiqiu, Yi Weiguo

Hunan Chemical Vocational Technology College, Zhuzhou 412004

Received:2017-07-25 Revised:2017-10-16 Published:2017-10-31
Contact: 10.6023/cjoc201707029 E-mail:wgyi_hunan@126.com
Supported by:
Project supported by the Scientific Research Fund of Hunan Provincial Education Department (No. 15C0464).

1. Ultrasonic-Assisted Synthesis of 2-Sulfonyl Nitrogen Heterocyclic Compounds.PDF(540KB)

Abstract

A facile and convenient ultrasonic-assisted method for the synthesis of 2-sulfonyl nitrogen heterocyclics has been developed. Using bromo-tris-pyrrolidino-phosphonium hexafluorophosphate (PyBroP) as catalyst, the reactions were carried out under ultrasound irradiation condition at room temperature for 1.0 h, and the 2-sulfonyl nitrogen heterocyclics were obtained in good yields with nitrogen heterocyclic N-oxides and sulfinic acid as raw materials. The reaction has the advantages of good substrate suitability, short reaction times and high yields, which provides a efficient approach for the synthesis of 2-sulfonyl nitrogen heterocyclics and their derivatives.

Key words: 2-sulfonyl nitrogen heterocyclics, nitrogen heterocyclic N-oxides, sulfinic acids, ultrasound-assisted

Cite this article

Lan Lixin, Xiao Jie, Xiao Huaiqiu, Yi Weiguo. Ultrasonic-Assisted Synthesis of 2-Sulfonyl Nitrogen Heterocyclic Compounds[J]. Chin. J. Org. Chem., 2018, 38(2): 492-497.

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超声促进2-磺酰基氮杂环化合物的合成研究

Ultrasonic-Assisted Synthesis of 2-Sulfonyl Nitrogen Heterocyclic Compounds

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