Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions

doi:10.6023/cjoc201804031

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (8): 1885-1896.DOI: 10.6023/cjoc201804031 Previous Articles Next Articles

Special Issue: 碳氢活化合辑2018-2019；元素有机化学合辑2018-2019

Reviews

碱土金属促进氢官能团化反应的研究进展

李园园^a,b,d, 程玉华^a, 单春晖^c, 张敬^e, 徐冬冬^c, 白若鹏^c, 屈凌波^d, 蓝宇^c,d

a 重庆第二师范学院生物与化学工程学院重庆 400067;
b 重庆第二师范学院脂质资源与儿童日化品协同创新中心重庆 400067;
c 重庆大学化学化工学院重庆 401331;
d 郑州大学化学与分子工程学院郑州 450006;
e 济宁学院化学与化工系济宁 272001

收稿日期:2018-04-16 修回日期:2018-05-11 发布日期:2018-05-17
通讯作者: 蓝宇 E-mail:lanyu@cqu.edu.cn
基金资助:
重庆市科委基金（基础研究与前沿探索）（No.cstc2017jcyjAX0371）、重庆第二师范学院科技协同创新平台建设（No.2017XJPT01）、重庆第二师范学院校级重点项目（No.KY201704A）及重庆第二师范学院博士启动基金（No.2017BSRC001）资助项目.

Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions

Li Yuanyuan^a,b,d, Cheng Yuhua^a, Shan Chunhui^c, Zhang Jing^e, Xu Dongdong^c, Bai Ruopeng^c, Qu Lingbo^d, Lan Yu^c,d

a College of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067;
b Cooperative Innovation Center of Lipid Resources and Children's Daily Chemicals, Chongqing University of Education, Chongqing 400067;
c School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331;
d College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450006;
e Department of Chemistry and Chemical Engineering, Jining University, Jining 272001

Received:2018-04-16 Revised:2018-05-11 Published:2018-05-17
Contact: 10.6023/cjoc201804031 E-mail:lanyu@cqu.edu.cn
Supported by:
Project supported by the Basic and Frontier Research Project of Chongqing Science and Technology Commission (No. cstc2017jcyjAX0371), the Project of Science and Technology Collaborative Innovation Platform Construction of Chongqing University of Education (No. 2017XJPT01), the University-level Key Projects of Chongqing University of Education (No. KY201704A), and the Scientific Research Foundation of Chongqing University of Education (No. 2017BSRC001).

Alkaline-earth-metal compounds have been widely concerned due to its abundant reserve and the low-cost. In recent years, alkaline-earth-metal catalysis has achieved great progress in dehydrocoupling, hydroboration, hydrophosphination, hydroamination, hydrosilylation reactions experimentally and therotically. These types of reaction and catalytic mechanism, leading to indentify the role of alkaline-earth-metal in hydrogenation and dehydrogenation reaction are summarized. These reactions, in which the metal-hydride act as active species, generally undergo the reaction pathway involving the cleavage and formation of the metal-hydride covalent bond. The reaction features and mechanisms are generally recognized accrossing to the classification and discussion of these reactions, which would provide guidance for further development of alkaline-earth-metal catalysis.

Key words: alkaline-earth-metals catalyst, hydrofunctionalization reaction, mechanism study, recent advance

Cite this article

Li Yuanyuan, Cheng Yuhua, Shan Chunhui, Zhang Jing, Xu Dongdong, Bai Ruopeng, Qu Lingbo, Lan Yu. Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions[J]. Chin. J. Org. Chem., 2018, 38(8): 1885-1896.

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碱土金属促进氢官能团化反应的研究进展

Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions

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