Preparation and Properties of Supramolecular Organogel Based on Iodine-Functionalized Pillar[5]arene

doi:10.6023/cjoc201805003

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (10): 2741-2746.DOI: 10.6023/cjoc201805003 Previous Articles Next Articles

Special Issue: 有机超分子化学合辑

Notes

基于碘功能化柱[5]芳烃超分子有机凝胶的制备和性能

陈进发, 刘茜, 韩冰冰, 丁金东, 张有明, 林奇, 姚虹, 魏太保

西北师范大学化学化工学院教育部生态环境相关材料重点实验室甘肃省高分子材料重点实验室兰州 730070

收稿日期:2018-05-01 修回日期:2018-05-28 发布日期:2018-06-15
通讯作者: 魏太保,E-mail:weitaibao@126.com E-mail:weitaibao@126.com
基金资助:
国家自然科学基金（Nos.21662031，21661028，21574104，21262032）资助项目.

Preparation and Properties of Supramolecular Organogel Based on Iodine-Functionalized Pillar[5]arene

Chen Jinfa, Liu Xi, Han Bingbing, Ding Jindong, Zhang Youming, Lin Qi, Yao Hong, Wei Taibao

Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education;Key Laboratory of Polymer Materials of Gansu Province;College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received:2018-05-01 Revised:2018-05-28 Published:2018-06-15
Contact: 10.6023/cjoc201805003 E-mail:weitaibao@126.com
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21662031, 21661028, 21574104, 21262032).

1. Preparation and Properties of Supramolecular Organogel Based on Iodine-Functionalized Pillar[5]arene.PDF(742KB)

Abstract

Pillararenes, a new kind of macrocyclic aromatic compounds, are closely attracted because it was used to construct supramolecular gels. In this paper, an iodine-functionalized pillar[5]arene was designed and synthesized. This pillar[5]arene can form a stable supramolecular organogel in cyclohexanol, and phase transition temperature is approximately 96 ℃. The formation process of the organogel was characterized by concentration dependent ¹H NMR spectrum, 2D NOESY experiment, X-ray diffraction (XRD) powder diffraction and scanning electron microscope. The experiment results showed that a sheet-like structure was formed in self-assembly process of iodine-functionalized pillar[5]arene. Meanwhile, the fluorescent recognition properties of organogel were studied. With the addition of 0.5 equiv. of various metal ions (Fe³⁺, Ag⁺, Ca²⁺, Co²⁺, Ni²⁺, Cd²⁺, Pb²⁺, Zn²⁺, Cu²⁺, Mg²⁺ and Hg²⁺) onto the organogel, Hg²⁺ and Ag⁺ can cause blue fluorescence quenching of the organogel after 10 min. Therefore, this gel can be used for fluorescent detection of Hg²⁺ and Ag⁺.

Key words: pillar [5]arene, supramolecular organogel, fluorescence detection, metal ion

Cite this article

Chen Jinfa, Liu Xi, Han Bingbing, Ding Jindong, Zhang Youming, Lin Qi, Yao Hong, Wei Taibao. Preparation and Properties of Supramolecular Organogel Based on Iodine-Functionalized Pillar[5]arene[J]. Chin. J. Org. Chem., 2018, 38(10): 2741-2746.

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基于碘功能化柱[5]芳烃超分子有机凝胶的制备和性能

Preparation and Properties of Supramolecular Organogel Based on Iodine-Functionalized Pillar[5]arene

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