Chemoenzymatic Relay Reaction and Its Applications in Highly Efficient and Green Synthesis of High-Value Chiral Compounds

doi:10.6023/cjoc201807038

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (3): 668-678.DOI: 10.6023/cjoc201807038 Previous Articles Next Articles

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化学-酶多步串联反应及其在高附加值手性化合物高效、绿色合成中的应用

廖旭^a, 蒋岩^b, 赖石林^a, 刘源岗^b, 王士斌^b, 熊兴泉^a

a 华侨大学材料科学与工程学院厦门 361021;
b 华侨大学化工学院厦门 361021

收稿日期:2018-07-23 修回日期:2018-09-25 发布日期:2018-10-26
通讯作者: 熊兴泉 E-mail:xxqluli@hqu.edu.cn
基金资助:
国家自然科学基金（No.21004024）、福建省自然科学基金（No.2016J01063）、福建省“高校新世纪优秀人才支持计划”（No.2012FJ-NCET-ZR03）、福建省“高校杰出青年科研人才培育计划”（No.11FJPY02）及华侨大学研究生科研创新基金（No.ZQN-YX103）资助项目.

Chemoenzymatic Relay Reaction and Its Applications in Highly Efficient and Green Synthesis of High-Value Chiral Compounds

Liao Xu^a, Jiang Yan^b, Lai Shilin^a, Liu Yuangang^b, Wang Shibin^b, Xiong Xingquan^a

a College of Materials Science and Engineering, Huaqiao University, Xiamen 361021;
b College of Chemical Engineering, Huaqiao University, Xiamen 361021

Received:2018-07-23 Revised:2018-09-25 Published:2018-10-26
Contact: 10.6023/cjoc201807038 E-mail:xxqluli@hqu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21004024), the Natural Science Foundation of Fujian Province (No. 2016J01063), the Program for New Century Excellent Talents in Fujian Province (No. 2012FJ-NCET-ZR03), the University Distinguished Young Research Talent Training Program of Fujian Province (No. 11FJPY02) and the Subsidized Project for Postgraduates' Innovative Fund in Scientific Research of Huaqiao University (No. ZQN-YX103).

Compared with traditional chemical catalysis or enzymatic synthesis, chemoenzymatic relay reaction is a simpler, more efficient and economical method. It not only has the advantages of high efficiency and selectivity of enzyme catalysis, but also has the advantages of low price of synthetic raw materials, simple and high efficiency of synthetic process, green and friendly production environment, and excellent optical purity of the obtained product. Thus, chemoenzymatic relay synthesis methods have been widely used in the synthesis of high-value chiral compounds. In recent years, chemists have been committed to making chemoenzymatic catalytic conditions easier by changing catalysts and designing more reasonable ways, which could be used in more fields. In this review, the recent progress in the synthesis of chiral alcohols, epoxides, heterocyclics and other chiral compounds by using chemoenzymatic relay synthesis, such as enzyme and metal catalysis, enzyme and organic catalysis, enzyme and new reaction techniques, is reviewed, and the development trends of this field are also prospected.

Key words: chemoenzymatic, relay reaction, high-value chiral compound, enzyme-metal catalysis, enzyme-organic catalysis

Cite this article

Liao Xu, Jiang Yan, Lai Shilin, Liu Yuangang, Wang Shibin, Xiong Xingquan. Chemoenzymatic Relay Reaction and Its Applications in Highly Efficient and Green Synthesis of High-Value Chiral Compounds[J]. Chin. J. Org. Chem., 2019, 39(3): 668-678.

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化学-酶多步串联反应及其在高附加值手性化合物高效、绿色合成中的应用

Chemoenzymatic Relay Reaction and Its Applications in Highly Efficient and Green Synthesis of High-Value Chiral Compounds

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