Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (8): 2338-2342.DOI: 10.6023/cjoc201902016 Previous Articles     Next Articles

Special Issue: 元素有机化学合辑2018-2019



杜山山, 柴正祺, 胡静远, 张文雄, 席振峰   

  1. 北京大学化学与分子工程学院 北京分子科学国家研究中心生物有机与分子工程教育部重点实验室 北京 100871
  • 收稿日期:2019-02-18 修回日期:2019-03-25 发布日期:2019-04-08
  • 通讯作者: 张文雄
  • 基金资助:


Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P64- Ligand

Du Shanshan, Chai Zhengqi, Hu Jingyuan, Zhang Wen-Xiong, Xi Zhenfeng   

  1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871
  • Received:2019-02-18 Revised:2019-03-25 Published:2019-04-08
  • Contact: 10.6023/cjoc201902016
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21725201, 21890721, 21572005).

Direct synthesis of organophosphorus compounds from white phosphorus (P4) is of great significance because this process avoids the industry pollution synthetic methods and provides the possibilities for many novel phosphorus-containing compounds. A trinuclear rare-earth metal complex[{(η5-C5Me5)LuCl}3(THF)P6] [Li(THF)4] from lutetacyclopentadiene mediated P4 functionalization was isolated and characterized. This novel complex contains a bicyclo[3.1.0]-P64- ligand which is an unreported type. X-ray diffraction analysis shows that the bicyclo[3.1.0]-P64- ligand adopts a boat-like conformation. Three lutetium atoms coordinate to this ligand in η1, η3, η3 mode, respectively, and a novel[P6Lu3] cage has been formed. Density functional theory (DFT) calculations indicate that there are two three-center two-electron bonds.

Key words: polyphosphorus ligand, white phosphorus activation, rare-earth-metal complex