Recent Progress of Discrete Metallacycles Based on the Half-Sandwich Ir/Rh/Ru Motifs

doi:10.6023/cjoc201908009

Abstract

Discrete metallacycle complexes have attracted considerable attention because of their widely used in host-guest chemistry, gas adsorption, molecular recognition and catalysis. Thus exploring new framework complexes, studying their physical and chemical properties and applications have become one of the most active and exciting areas of inorganic chemistry, organic chemistry and supramolecular chemistry. Half-sandwich organometallic units based on ruthenium, iridium and rhodium are often utilized to prepare diverse metallacylce complexes due to the following advantages:the solubility of these metal complexes can be enhanced, the hemisphere of the metal center is perfectly shielded, minimizing the complexity of reactions, and the products with different structures are easily synthesized. In this paper, the synthesis and application of discrete type metal framework complexes with half-sandwich structures of ruthenium, iridium and rhodium are reviewed.

Key words: organometallic, half-sandwich, Ir/Rh/Ru, metallacycle

Cite this article

Liu Jinbao, Li Peng, Yao Zijian. Recent Progress of Discrete Metallacycles Based on the Half-Sandwich Ir/Rh/Ru Motifs[J]. Chinese Journal of Organic Chemistry, 2020, 40(2): 364-375.

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